The Search for a Super Battery

From electric vehicles to grid storage for renewables, batteries are key components in many of tomorrow’s innovations. But current commercialized batteries face problems of price, efficiency, safety, and life-cycle. The television series, NOVA, is exploring many of those issues in the upcoming episode, “Search for the Super Battery.”

A preview of the episode by CBS News explores two innovators who are working toward the next big thing in battery technology.

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By: Mathew Wallenstein, Colorado State University

MicrobesWalk into your typical U.S. or U.K. grocery store and feast your eyes on an amazing bounty of fresh and processed foods. In most industrialized countries, it’s hard to imagine that food production is one of the greatest challenges we will face in the coming decades.

By the year 2050, the human population is projected to grow from 7.5 billion to nearly 10 billion. To feed them, we will need to almost double food production within just three decades, all in the face of increasing drought, herbicide and pesticide resistance, and in a world where the best cropland is already being farmed.

From the 1960s through the 1980s, international initiatives referred to collectively as the Green Revolution dramatically increased food production, largely by breeding crop varieties that were able to take advantage of man-made fertilizer and developing powerful pesticides and herbicides. But as we intensified agriculture, we also intensified its environmental impacts. They include soil erosion, reduced biodiversity and the release of greenhouse gases that drive climate change.

Today our ability to continuously push these systems to produce more crops year after year has largely stagnated, and is not keeping pace with rising demand. Clearly, new innovations are needed to change the way we grow food and make it more sustainable.

I am part of a new crop of scientists who are harnessing the power of natural microbes to improve agriculture. In recent years, genomic technology has rapidly advanced our understanding of the microbes that live on virtually every surface on Earth, including our own bodies. Just as our new understanding of the human microbiome is revolutionizing medicine and spawning a new probiotic industry, agriculture may be poised for a similar revolution.

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FloodA recent report published by the National Oceanic and Atmospheric Administration (NOAA) states that the global sea level could rise by as much as 8 feet by 2100.

A key force behind rising sea levels is climate change. A warming climate can cause seawater to expand and ice to melt, both of which lead to a rise in sea level. Because many people live in coastal areas across the globe, scientists have been monitoring the rising sea level closely due to its ability to displace families. According to NOAA, the global sea level has been rising at a rate between 0.04 to 0.1 inches per year since 1900.

However, that rate expected to greatly accelerate in the coming years.

“Currently, about 6 million Americans live within about 6 feet of the sea level, and they are potentially vulnerable to permanent flooding in this century. Well before that happens, though, many areas are already starting to flood more frequently,” Robert E. Kopp, co-author of the report, tells Rutgers Today. “Considering possible levels of sea-level rise and their consequences is crucial to risk management.”

The researchers came to this consensus after examining the latest published, peer reviewed science, while taking into account the recent information on the instability of the Antarctic ice-sheet.

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HydrogenNew research led by ECS Fellow John Turner, researcher at the National Renewable Energy Laboratory, demonstrates a pioneering, efficient way to make renewable hydrogen.

Hydrogen has many highly sought after qualities when he comes to clean energy sources. It is a simple element, high in energy, and produces almost zero pollution when burned. However, while hydrogen is one of the most plentiful elements in the universe, it doesn’t occur naturally as a gas – instead, it’s always combined with other elements. That’s where efforts in water-splitting come in.

If researchers can effectively split water molecules into oxygen and hydrogen, new branches of hydrogen production could emerge.

Turner and his team are working on a method to boost the longevity of highly efficient photochatodes in photoelectrochemical water-splitting devices.

“Electrochemistry nowadays is really the key,” Turner told ECS during a podcast in 2015. “We have fuel cells, we have electrolyzers, and we have batteries. All of the things going on in transportation and storage, it all comes down to electrochemical energy conversion.”

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Battery fires led to the recall of nearly 2 million Samsung Galaxy Note 7 smartphones. In order to address this safety concern, researchers at Stanford University have identified 21 solid electrolytes for solid state batteries that could power the next-generation of electronics.

“Electrolytes shuttle lithium ions back and forth between the battery’s positive and negative electrodes,” says lead author of the study Austin Sendek, a doctoral candidate at Stanford University, who worked with ECS member Yi Cui on this research. “Liquid electrolytes are cheap and conduct ions really well, but they can catch fire if the battery overheats or is short-circuited by puncturing.”

As demands from the electronics industry grow and consumers become more suspicious of lithium-ion technology, researchers have started focusing efforts on creating an all-solid-state battery.

“The main advantage of solid electrolytes is stability,” Sendek says. “Solids are far less likely to blow up or vaporize than organic solvents. They’re also much more rigid and would make the battery structurally stronger.”

Posted in Batteries
Catalysts

Image: MIT

The future of renewable energy heavily depends on energy storage technologies. At the center of these technologies are oxygen-evaluation reactions, which make possible such processes as water splitting, electrochemical carbon dioxide reduction, and ammonia production.

However, the kinetics of the oxygen-evolution reactions tend to be slow. But metal oxides involved in this process have catalytic activities that vary over several orders of magnitude, with some exhibiting the highest such rates reported to date. The origins of these activates are not well-understood by the scientific community.

A new study from MIT, led by 2016 winner of the Battery Division Research Award, Yang Shao-Horn, shows that in some of these catalysts, the oxygen does not only come from surrounding water molecules – some actually come from within the crystal lattice of the catalyst material itself.

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BiofuelBiofuels have become a promising potential alternative for traditional fossil fuels. However, producing biofules only make sense if the greenhouse gasses emitted are less than other means of producing energy.

According to new research, sugarcane and nepiegrass could be two of the most promising candidates for biofuel production due to their ability to isolate more carbon dioxide in the soil than is lost in the atmosphere.

Sugarcane and nepiegrass both have large carbon-storing root biomass that can offset the carbon dioxide emitted during cultivation. To test this, researchers observed these plants in Hawaii over a two year period, measuring both the above- and below-ground biomass and resulting greenhouse gas flux.

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Carbon dioxideGlobally, carbon dioxide in the number one contributor to harmful greenhouse gas emissions. These emissions have been linked to the acceleration of climate change, leading to such devastating effects as rising sea levels that displace communities and radical local climates that hurt agriculture.

But what is you could turn that CO2 into baking powder?

That’s what one company in India is setting out to do. A chemical plant in the city of Tuticorin is teaming up with India’s Carbon Clean Solutions to save 60,000 tons of last year’s CO2 emissions.

“I am a businessman. I never thought about saving the planet,” says Ramachadran Gopalan, owner of the plant that is capturing CO2 from coal-powered boilers, to BBC Radio 4. “I needed a reliable stream of CO2, and this was the best way of getting it.”

While Gopalan may not have thought about saving planet, the team at Carbon Clean Solutions has.

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Renewable liquid fuelRenewable energy is on the rise, but how we store that energy is still up for debate.

“Renewable energy is growing, but it’s intermittent,” says Grigorii Soloveichik, program director at the United States Department of Energy’s Advanced Research Projects Agency. “That means we need to store that energy and we have two ways to do that: electricity or liquid fuels.”

According to Soloveichik, electricity and batteries are sufficient for short term energy storage, but new technologies such as liquid fuels derived from renewable energy must be considered for long term storage.

During the PRiME 2016 meeting in October, Soloveichik presented a talk titled, “Development of Transformational Technologies,” where he described the advantages that carbon neutral liquid fuels have over other convention means – such as batteries – for efficient, affordable, long term storage for renewable energy sources.

Rise of renewables

In the United States, 16.9 percent of electricity generation comes from renewables – a 9.3 percent increase since 2015. Globally, climate talks such as the Paris Agreement help bolster the rise of renewable energy around the world. Soloveichik expects that growth to continue in light of the affordability of clean energy technologies and government mandates that aim at environmental protection and a reduction of the carbon footprint. However, the continued rise in renewable dependence will impact the current grid infrastructure.

“More renewables will result in more stress on the grid,” Soloveichik says. “All of these new sources are intermittent, so we need to be able to store huge amounts of energy.”

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France Builds First Solar Road

Solar roadRecent trends in solar technology have led to transforming mundane surface to energy harvesting powerhouses. First, Elon Musk proposed his new solar roof. Now, rural France is taking a page from that book with the recent paving of paths with solar panels.

The solar road is part of the Wattway projects, which aims to pave nearly 3,000 roadways with solar panel tiles.

According to reports, the 1 kilometer road will produce 767 kWh hours of electricity every day. Because the panels are flat, the amount of energy produced is limited. However, the energy generated is enough to power an average family home for one year.

“We are still experimenting with Wattway,” says Jean-Charles Broizat, CEO of Wattway, in a statement. “Building an application site of this magnitude is a real opportunity for our innovation. This application site has enabled us to improve our process of installing photovoltaic panels as well as their manufacture, in order to optimize our solution as best as possible.”