Does this summer feel a little warmer than usual? Well, that’s because it is.

According to NASA, the first six months of 2016 have been the warmest half-year ever recorded. Pair that with the smallest monthly Artic Sea ice extent in that same period of time, and these two indicators give a grim image of the accelerating pace of climate change.

In a report, NASA states that the global temperature has increased by 2.4°F since record keeping began in the 1800s. Additionally, Artic Sea ice has been declining at a rate of 13.4 percent per decade.

“It has been a record year so far for global temperatures, but the record high temperatures in the Arctic over the past six months have been even more extreme,” says Walt Mkeier, a sea ice researcher with NASA. “This warmth as well as unusual weather patterns have led to the record low sea ice extents so far this year.”

If climate continues down this same path, the effects could be devastating for the world. However, electrochemical and solid state science may have some of the answers to mitigate climate change.

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As the landscape of energy harvesting evolves, so do the devices that store that energy. According to researchers from Toyohashi University, all-solid-state lithium rechargeable batteries are at the top of the list of promising future energy storage technologies due to their high energy density, safety, and extreme cycle stability.

ECS member Yoji Sakurai and a team from the university’s Department of Electrical and Electronic Information Engineering recently published a paper detailing their development to advance the all-solid-state batteries, which pushes past barriers related to electrochemical performance.

(MORE: Read Sakurai’s previously published paper in ECS Electrochemistry Letters.)

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Fuel cells have existed (at least in theory) since the early 1800s, but have spent much of their existence as laboratory curiosities. It wasn’t until the mid-1900s that fuel cells finally got their time in the spotlight with the first major application in the Gemini and Apollo space flights.

While fuel cells have moved forward in the competitive field of energy storage, there are still many barriers that researchers are attempting to overcome. Especially today, with society making a conscious effort to move toward more sustainable types of power, much emphasis has been put on solid oxide fuel cells and moving them from the lab to the market.

(MORE: Get additional information on the evolution of fuel cell technology.)

A team of researchers from Washington State University believes they may have taken a crucial step in doing just that.

Moving fuel cells forward

The team recently published a paper detailing what they believe to be a key step in SOFC improvement and eventually implementation in the marketplace. These small improvements could mean big changes.
SOFCs, unlike other types of fuel cells, do not require the use of expensive materials (i.e. platinum) to develop.

“Solid oxide fuel cells are very fuel flexible in contrast to other kinds of fuel cells, like alkaline fuel cells,” Subhash Singhal, Battelle Fellow Emeritus at Pacific Northwest National Laboratory and esteemed fuel cell expert, told ECS in a previous interview. “Solid oxide fuel cells can use a variety of fuel: natural gas, coal gas, and even liquid fuels like diesel and gasoline.”

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From Bourbon to Batteries

There is no short supply of bourbon in Kentucky. But like many products, the distillation of the state’s unofficial beverage produces a sludgy waste known as bourbon stillage. The question for one researcher from the University of Kentucky’s Center for Applied Energy Research was how to repurpose that waste into something with tremendous potential.

To answer that question, ECS member Stephen Lipka and his Electrochemical Power Sources group set out to transform the bourbon stillage through a process called hydrothermal carbonization, where the liquid waste gets a dose of water and heat to produce green materials.

(MORE: See more of Lipka’s work in the ECS Digital Library.)

“In Kentucky, we have this stillage that contains a lot of sugars and carbohydrates so we tried it and it works beautifully,” says Lipka. “We take these [green materials] and we then do additional post-processing to convert it into useful materials that can be used for batteries.”

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toyota-collage

From left to right: Elizabeth Biddinger, City College of New York; Joaquin Rodriguez Lopez, University of Illinois at Urbana-Champaign; Joshua Snyder, Drexel University

The ECS Toyota Young Investigator Fellowship Selection Committee has selected three recipients who will receive a minimum of $50,000 each for fellowships for projects in green energy technology. The winners are Professor Elizabeth Biddinger, City College of New York; Professor Joaquin Rodriguez Lopez, University of Illinois at Urbana-Champaign; and Professor Joshua Snyder, Drexel University.

The ECS Toyota Young Investigator Fellowship, a partnership between The Electrochemical Society and Toyota Research Institute of North America (TRINA), a division of Toyota Motor Engineering & Manufacturing North America, Inc. (TEMA), is in its second year. A diverse applicant pool of more than 100 young professors and scholars pursuing innovative electrochemical research in green energy technology responded to ECS’s request for proposals.

“Scientists and engineers seek to unveil what is possible and to exploit that knowledge to provide solutions to the myriad of problems facing our world,” says ECS Executive Director Roque Calvo. “We are proud to have the continued support of Toyota in this never ending endeavor to uncover new frontiers and face new challenges.”

The ECS Toyota Young Investigator Fellowship aims to encourage young professors and scholars to pursue research in green energy technology that may promote the development of next-generation vehicles capable of utilizing alternative fuels.

Global development of industry and technology in the 20th century increased production of vehicles and the growing population have resulted in massive consumption of fossil fuels. Today, the automotive industry faces three challenges regarding environmental and energy issues:

(1) Finding a viable alternative energy source as a replacement for oil
(2) Reducing CO2 emissions
(3) Preventing air pollution

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A new collaborative study from Delft University and École Polytechnique Fédérale de Lausanne (EPFL) shows a highly-efficient, simple way to produce hydrogen through solar water-splitting at a low cost.

The team of researchers, including 2016 PRiME Plenary speaker Michael Graetzel, state that by using Earth-abundant catalysts and solar cells, effective water-splitting systems could sustainably produce affordable hydrogen.

Graetzel, known for his low-cost, high-efficiency solar cell that won him the 2010 Millennium Technology Grand Prize, helped lead the effort by separating the positive and negative electrodes using a bipolar membrane, leading to a simple yet effective new method.

Hydrogen economy

The technology behind water-splitting is essential in an economy shifting toward more hydrogen use as alternative fuels. While efficient methods of generating hydrogen do currently exist, the techniques used to produce the gas consume large amounts of fossil fuels.

Moving toward a hydrogen economy could help alleviate the effects of climate change, but only if the means used to produce the gas are also sustainable. This is where water-splitting comes in.

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A new report by TechXplore examines a recently published review paper on the potential in nanomaterials for rechargeable lithium batteries. In the paper, lead-author and ECS member Yi Cui of Stanford University, explores the barriers that still exist in lithium rechargeables and how nanomaterials may be able to lend themselves to the development of high-capacity batteries.

When trying to design affordable batteries with high-energy densities, researchers have encountered many issues, including electrode degradation and solid-electrolyte interphase. According to the paper’s authors, possible solutions for many of these hurdles lie in nanomaterials.

Cui’s comprehensive overview of rechargeable lithium batteries and the potential of nanaomaterials in these applications came from 100 highly-reputable publications, including the following ECS published papers:

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Modified Cathode

Cathode particles treated with the carbon dioxide-based mixture show oxygen vacancies on the surface.
Image: Laboratory for Energy Storage and Conversion, UC San Diego

An international team of researchers has recently demonstrated a 30 to 40 percent increase in the energy storage capabilities of cathode materials.

The team, led by ECS member and 2016 Charles W. Tobias Young Investigator Award winner, Shirley Meng, has successfully treated lithium-rich cathode particles with a carbon dioxide-based gas mixture. This process introduced oxygen vacancies on the surface of the material, allowing for a huge boost to the amount of energy stored per unit mass and proving that oxygen plays a significant role in battery performance.

This greater understanding and improvement in the science behind the battery materials could accelerate developments in battery performance, specifically in applications such as electric vehicles.

(READ: “Gas-solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries“)

“We’ve uncovered a new mechanism at play in this class of lithium-rich cathode materials,” says Meng, past guest editor of JES Focus Issue on Intercalation Compounds for Rechargeable Batteries. “With this study, we want to open a new pathway to explore more battery materials in which we can control oxygen activity.”

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Carbon Dioxide

Image: CC0

With atmospheric greenhouse gas levels at their highest in history, many researchers have been contemplating one question: How can we reutilize carbon dioxide?

One new study reports a new catalyst with the ability to execute highly selective conversion of carbon dioxide into ethylene, producing an important source material for the chemical industry.

The push to convert carbon dioxide into useful chemicals is not a completely novel concept among the scientific community. For this study, researchers opted to make the process more efficient by implementing a new catalyst with higher selectivity to produce more useful chemicals and less unwanted byproducts.

Ruhr-Universitӓt Bochum PhD student and ECS student member, Hemma Mistry, veered away from the traditional catalyst used in this process and instead opted for copper films treated with oxygen or hydrogen plasmas. By doing this, Mistry was able to alter surface properties for optimal performance.

(MORE: Read Mistry’s past ECS Meeting Abstract entitled, “Selectivity Control in the Electroreduction of CO2 over Nanostructured Catalysts.”)

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When lithium-ion pioneers M. Stanley Whittingham, Adam Heller, Michael Thackeray, and of course, John Goodenough were in the initial stages of the technology’s development in the 1970s through the late 1980s, there was no clear idea of just how monumental the lithium-based battery would come to be. Even up to a few years ago, the idea of an electric vehicle or renewable grid dependent on lithium-ion technology seemed like a pipe dream. But now, electric vehicles are making their way to the mainstream and with them comes the commercially-driven race to acquire lithium.

Just look at the rise of Tesla and success of the Nissan LEAF. Not only are these cars speaking to a real concern for environmental protection, they’re also becoming the more affordable option in transportation. For example, the LEAF goes for less than $25,000 and gets more than 80 miles per charge. Plus, electric vehicles can currently run on electricity that’s costing around $0.11 per kWh, which is roughly equivalent to $0.99 per gallon. The last year alone saw a 60 percent spike in the sale of electric vehicles.

“Electric cars are just plain better,” says James Fenton, director of the Florida Solar Energy Center and newly appointed ECS Secretary. “They’re cheaper to buy up front and they’re cheaper to operate, which years ago, was not the case.”

All things considered, lithium may just be the number one commodity of our time.

But this movement is not specific to the U.S. alone. In Germany – a country dedicated to a renewable future – there is a mandate that all new cars in the country will have to be emission-free by 2030. Similarly in Norway, the government is looking to ban gasoline-powered cars by 2025.

So with the transportation sector heading away from gasoline-powered cars and toward lithium battery-based vehicles globally, what will that do to lithium supplies?

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