Researchers have found a way to use rust to build a solar-powered battery.Image: Flickr

Researchers have found a way to use rust to build a solar-powered battery.
Image: Diego Torres Silvestre

What happens when corrosion meets energy? For researchers at Stanford University, the marriage of those two uniquely electrochemical topics could yield an answer to large-scale solar power storage.

The question of how to store solar power when the sun goes down has been on the forefront of scientific discussion. While electrochemical energy storage devices exist, they are typically either too expensive to work on a large-scale or not efficient enough.

Building a solar-powered battery

New research shows that metal oxides, such as rust, can be fashioned into solar cells capable of splitting water into hydrogen and oxygen. The research could be looked at revelatory, especially when considering large-scale storage solutions, because of its novel heat attributes.

While we knew the promising solar power potential of metal oxides before, we believed that the efficiency of cells crafted from these materials would be very low. The new study, however, disproves that theory.

The team showed that as the cells grow hotter, efficiency levels increase. This is a huge benefit when it comes to large-scale, solar energy conversion and it the polar opposite of the traditional silicon solar cell.

“We’ve shown that inexpensive, abundant, and readily processed metal oxides could become better producers of electricity than was previously supposed,” says William Chueh, an assistant professor of materials science and engineering.

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Globally, carbon dioxide is the number one contributor to harmful greenhouse gas emissions. These emissions accelerate climate change, leading to such devastating effects as rising sea levels that can dislocate families and radical local climates that hurt food production levels.

But what if we could turn those harmful emissions into useable fuels through a simple, one-step process?

Researchers have proven that through a process combining concentrated light, heat, and high pressure, carbon dioxide and water could be directly converted into usable liquid hydrocarbon fuels.

Not only would this effort offer some relief in the energy infrastructure, it would also aid efforts against climate change by removing carbon dioxide from the atmosphere.

“Our process also has an important advantage over battery or gaseous-hydrogen powered vehicle technologies as many of the hydrocarbon products from our reaction are exactly what we use in cars, trucks and planes, so there would be no need to change the current fuel distribution system,“ said Frederick MacDonnell, co-principal investigator of the project.

The corresponding paper was published in the Proceedings of the National Academy of Sciences.

“We are the first to use both light and heat to synthesize liquid hydrocarbons in a single stage reactor from carbon dioxide and water,” said Brian Dennis, co-principal investigator of the project. “Concentrated light drives the photochemical reaction, which generates high-energy intermediates and heat to drive thermochemical carbon-chain-forming reactions, thus producing hydrocarbons in a single-step process.”

Bill & Melinda Gates FoundationThe Bill & Melinda Gates Foundation has been fighting the good fight on many fronts over the years, including poverty, women’s equality, and of course, energy.

In their 2016 annual letter, the private foundation looked at the issue of access to energy. According to Bill Gates, 1.3 billion people – or 18 percent of the world’s population – live without electricity to light their homes.

Energy crisis

Many energy trouble areas exist in sub-Saharan Africa, where 7 out of 10 people live in the dark. The same problems exist in parts of Asia and India where more than 300 million people lack access to electricity.

(MORE: Take a look at the work that ECS has done with the Gates Foundation to tackle critical issues in water and sanitation.)

There are still many parts of the world that have yet to reap the benefits of Thomas Edison’s incandescent light bulb.

But it’s not just about light. Energy allows better medical care through functioning hospitals, greater educational efforts through functioning schools, and even more food through the powering of agricultural devices.

Renewable energy revolution

Not only is the provision of energy to all people essential, but the research into finding a clean, efficient way to do so is also crucial. ECS members and scientists across the globe are currently making effort to combat climate change, which is consequentially poised to hit the world’s poor the hardest.

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Nuclear PosterThe U.S. Department of Energy recently released a new series of posters illuminating a new generation of sustainable energy and green jobs. The series is reminiscent of the famous imagery created for the Works Progress Administration, only this time, the images depict a renewable energy revolution.

The posters accompany a report on the energy accomplishments from the American Recovery and Reinvestment Act, which was signed into law seven years ago by President Obama.

(MORE: See all the the posters from the department of energy.)

The newly established law created the Section 1705 Loan Guarantee Program, which worked to spur economic growth while creating new jobs and saving existing ones.

Some of the key accomplishments of the act include the creating of 10,000 jobs in the energy industry, $16.1 billion in loans for renewable energy projects, and a newly developed infrastructure that can power an additional one million American homes annually.

The Recovery Act also launched utility-grade photovoltaic solar plants in the U.S. Prior to signing the act into law in 2009, there weren’t any plants larger than 100 megawatts in the country. Now, five major plants are producing significant amounts of energy and 28 more are scheduled for the future.

Overall, the posters remind citizens of the positive accomplishments that can be achieved when government and science work together as well as give us all a visual image of an optimistic view of a renewable future.

Powering Fuel Cells with Wastewater

The word “renewable” often triggers thoughts of solar and wind in the realm of energy technology.

Two researchers from Virginia Tech are now trying to change that perception, focusing on maximizing the amount of electricity that can be generated from the wastewater we flush down the toilet.

They’re turning poo into power.

(MORE: See what ECS scientists are doing to transform wastewater.)

“Tracing the bacteria gave us a major piece of the puzzle to start generating electricity in a sustainable way,” said Xueyang Feng, co-author of the study. “This is a step toward the growing trend to make wastewater treatment centers self-sustaining in the energy they use.”

Chemically Storing Solar Power

Solar Chemical Energy

UV light can now be stored at much higher temperatures thanks to the development of a photo-electrochemical cell.
Image: Advanced Functional Materials

A new photo-electrochemical cell has been developed with the potential to chemically store the sun’s energy at high temperatures.

It’s a concept pulled directly from nature: plants absorb sunlight and store it chemically. While the concept is simple, replicating it on a large scale has proven quite difficult.

Current photovoltaic technology can convert sunlight to electricity, but as temperatures increase, the solar cell efficiency consequently decreases.

Storage at high temperatures

The new concept developed by scientists at Vienna University of Technology looks to overcome these issues. Through a combination of specialized new materials, researchers were able to combine high temperature photovoltaics with an electrochemical cell.

From that point, the sun’s rays can be directly used to pump oxygen ions through a solid oxide electrolyte and the UV light is subsequently stored chemically. This breakthrough allows for the system to work at higher temperatures than ever before.

Mirroring a concept from nature

“This would allow us to concentrate sunlight with mirrors and build large-scale plants with a high rate of efficiency,” said Georg Brunauer, lead author of the study. “Our cell consists of two different parts – a photoelectric part on top and an electrochemical part below. In the upper layer, ultraviolet light creates free charge carriers, just like in a standard solar cell.”

Researchers hope this could lead the splitting water and the production of hydrogen.

“We want to understand the origin of these effects by carrying out a few more experiments, and we hope that we will be able to improve our materials even further,” Brunauer said. “This goal is within reach, now that we have shown that the cell is working.”

Sustainable Battery

The new carbon-based material for sodium-ion batteries can be extracted from apples.
Image: KIT

The saying goes: an apple a day keeps the doctor away; but in this case, an apple may be the answer to the next generation of energy storage technology.

ECS member Stefano Passerini of the Karlsruhe Institute of Technology is leading a study to extract carbon-based materials for sodium-ion batteries from organic apple waste.

Developing batteries from waste

This new development could help reduce the costs of future energy storage systems by applying a cheap material with excellent electrochemical properties to the already promising field of sodium-ion batteries.

(MORE: Read more research by Passerini.)

Many researchers are currently looking to sodium-ion batteries as the next generation of energy storage, with the ability to outpace the conventional lithium-ion battery.

The future of sodium-ion batteries

Interest in sodium-ion batteries dates back to the 1980s, but discoveries haven’t taken off until recently. Researchers are now finding way to combat low energy densities and short life cycles through using novel materials such as apples.

(MORE: Read the full paper in ChemElectroChem.)

Sodium-ion batteries could prove to be the next big thing in large scale energy storage due to the high abundance of materials used in development and the relatively low costs involved.

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Krishnan Rajeshwar

Krishnan Rajeshwar, ECS senior vice president and co-founder of UTA’s Center for Renewable Energy, Science and Technology

New research headed by ECS senior vice president Krishnan Rajeshwar has developed “green fuels” to power cars, home appliances, and even impact critical energy storage devices.

Solar fuels addressing global issues

Rajeshwar’s research works to address critical global and environmental issue by creating an inexpensive way to generate fuel from harmful emissions such as carbon dioxide.

(MORE: Read additional publications by Rajeshwar.)

The University of Texas at Arlington professor and 35 year ECS member has developed a novel high-performing material for cells that harness sunlight to split carbon dioxide and water into usable fuels like methanol and hydrogen gas.

From harmful to helpful

“Technologies that simultaneously permit us to remove greenhouse gases like carbon dioxide while harnessing and storing the energy of sunlight as fuel are at the forefront of current research,” Rajeshwar said. “Our new material could improve the safety, efficiency and cost-effectiveness of solar fuel generation, which is not yet economically viable.”

(MORE: Read the full study as published in ChemElectroChem Europe.)

This from University of Texas at Arlington:

The new hybrid platform uses ultra-long carbon nanotube networks with a homogeneous coating of copper oxide nanocrystals. It demonstrates both the high electrical conductivity of carbon nanotubes and the photocathode qualities of copper oxide, efficiently converting light into the photocurrents needed for the photoelectrochemical reduction process.

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Clean Energy from Water

For most of history, fuel cells existed only as laboratory curiosities. As far back as 1839, the English scientist William Grove had the idea that the reactants of a battery could be gases fed into it from external tanks.

Since their humble beginnings, fuel cells have come a far to prove as a viable alternative to combustion. Currently, researchers at the University of Basel are studying how sunlight could split water into hydrogen and oxygen, creating a fuel cell that could produce clean energy from water.

(MORE: Read “Battery and Fuel Cell Technology.”)

Artificial photosynthesis has proven to be one of the most promising tools in producing clean, renewable resources. This process occurs when water is photo-electrochemically, with the aid of sunlight, separated into its H2 and O2 components.

Of the two reactions that occur, water oxidation typically provides researchers with the most hurdles to overcome. The new research works to develop an efficient, sustainable water oxidation catalyst.

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Morocco has officially opened the Noor I power plan — a massive solar power plant in the Sahara Desert that is poised to provide renewable energy to more than one million Moroccans.

Projects show the Noor I power plants with the capability of generating up to 160 megawatts of power. Thousands of solar panels cover an expansive piece of the desert, making it one of the world’s biggest solar thermal power plants.

But Morocco is well on the way to developing the single largest solar power production facility in the world, with Noor II and Noor III already underway.

This from NPR:

Morocco currently relies on imported sources for 97 percent of its energy consumption, according to the World Bank, which helped fund the Noor power plant project. Investing in renewable energy will make Morocco less reliant on those imports as well as reduce the nation’s long-term carbon emissions by millions of tons.

Read the full article.

Because of the climate in the Sahara Desert, the systems will work by capturing the sun’s energy as heat and converting water into steam, thus turning the turbines.

This differs from a traditional photovoltaic system, where the thermal system carries the ability to function without direct sunlight. Additionally, energy storage technologies are not necessary for evening use.