Catalysts

Image: MIT

The future of renewable energy heavily depends on energy storage technologies. At the center of these technologies are oxygen-evaluation reactions, which make possible such processes as water splitting, electrochemical carbon dioxide reduction, and ammonia production.

However, the kinetics of the oxygen-evolution reactions tend to be slow. But metal oxides involved in this process have catalytic activities that vary over several orders of magnitude, with some exhibiting the highest such rates reported to date. The origins of these activates are not well-understood by the scientific community.

A new study from MIT, led by 2016 winner of the Battery Division Research Award, Yang Shao-Horn, shows that in some of these catalysts, the oxygen does not only come from surrounding water molecules – some actually come from within the crystal lattice of the catalyst material itself.

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Waste waterA new study led by ECS member Haluk Beyenal reveals a novel type of cooperative photosynthesis with potential applications in waste treatment and bioenergy production.

The research details a unique metabolic process observed for the first time in a pair of bacteria, which could be used to engineer microbial communities. Beyenal and his team honed in on a bacterium known as Prosthecochloris aestaurii, which is able to photosynthesize by using sunlight and elemental sulfur or hydrogen sulfide.

This from Washington State University:

The researchers noticed that P. aestuarii tended to gather around a carbon electrode, an electricity conductor that they were operating in Hot Lake. The researchers isolated and grew P. aestuarii and determined that, similar to the way half of a battery works, the bacterium is able to grab electrons from a solid electrode and use them for photosynthesis. The pink-colored Geobacter sulfurreducens meanwhile, is known for its ability to convert waste organic matter to electricity in microbial fuel cells. The bacterium is also used in environmental cleanup.

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BiofuelBiofuels have become a promising potential alternative for traditional fossil fuels. However, producing biofules only make sense if the greenhouse gasses emitted are less than other means of producing energy.

According to new research, sugarcane and nepiegrass could be two of the most promising candidates for biofuel production due to their ability to isolate more carbon dioxide in the soil than is lost in the atmosphere.

Sugarcane and nepiegrass both have large carbon-storing root biomass that can offset the carbon dioxide emitted during cultivation. To test this, researchers observed these plants in Hawaii over a two year period, measuring both the above- and below-ground biomass and resulting greenhouse gas flux.

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Static Electricity’s Tiny Sparks

By: Sebastian Deffner, University of Maryland, Baltimore County

Static electricityStatic electricity is a ubiquitous part of everyday life. It’s all around us, sometimes funny and obvious, as when it makes your hair stand on end, sometimes hidden and useful, as when harnessed by the electronics in your cellphone. The dry winter months are high season for an annoying downside of static electricity – electric discharges like tiny lightning zaps whenever you touch door knobs or warm blankets fresh from the clothes dryer.

Static electricity is one of the oldest scientific phenomena people observed and described. Greek philosopher Thales of Miletus made the first account; in his sixth century B.C. writings, he noted that if amber was rubbed hard enough, small dust particles will start sticking to it. Three hundred years later, Theophrastus followed up on Thales’ experiments by rubbing various kinds of stone and also observed the “power of attraction.” But neither of these natural philosophers found a satisfactory explanation for what they saw.

It took almost 2,000 more years before the English word “electricity” was first coined, based on the Latin “electricus,” meaning “like amber.” Some of the most famous experiments were conducted by Benjamin Franklin in his quest to understand the underlying mechanism of electricity – which is one of the reasons why his face smiles from the US$100 bill. People quickly recognized electricity’s potential usefulness.

Of course, in the 18th century people mostly made use of static electricity in magic tricks and other performances. For instance, Stephen Gray‘s “flying boy experiment” became a popular public demonstration: He’d use a Leyden jar to charge up the youth, suspended from silk cords, and then show how he could turn book pages via static electricity, or lift small objects just using the static attraction.

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Editors' Choice

An Editors’ Choice article is a special designation applied by the Journals’ Editorial Board to any article type. Editors’ Choice articles are transformative and represent a substantial advance or discovery, either experimental or theoretical. The work must show a new direction, a new concept, a new way of doing something, a new interpretation, or a new field, and not merely preliminary data.

Two Editors’ Choice articles were published in the Journal of The Electrochemical Society (JES) in December 2016.

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Carbon dioxideGlobally, carbon dioxide in the number one contributor to harmful greenhouse gas emissions. These emissions have been linked to the acceleration of climate change, leading to such devastating effects as rising sea levels that displace communities and radical local climates that hurt agriculture.

But what is you could turn that CO2 into baking powder?

That’s what one company in India is setting out to do. A chemical plant in the city of Tuticorin is teaming up with India’s Carbon Clean Solutions to save 60,000 tons of last year’s CO2 emissions.

“I am a businessman. I never thought about saving the planet,” says Ramachadran Gopalan, owner of the plant that is capturing CO2 from coal-powered boilers, to BBC Radio 4. “I needed a reliable stream of CO2, and this was the best way of getting it.”

While Gopalan may not have thought about saving planet, the team at Carbon Clean Solutions has.

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There’s a major player in the autonomous, electric car industry that may just outpace transportation mogul Tesla. Faraday Future, an American start-up focused on developing intelligent electric vehicles, just unveiled its first self-driving supercar called the FF91.

Faraday Future states that the vehicle’s 130 kWh battery delivers a range of 378 miles on a single charge. Additionally, 10 cameras, 13 radar sensors, and 12 ultrasonic sensors help power the vehicle’s autonomous abilities.

But Nick Samson, Faraday Future’s senior vice president of engineering, says that the FF91 is “more than just a car,” rather an “intelligent entity.”

In addition to the batter and self-driving tech, the FF91 boasts an infotainment system that allows passengers to watch TV based on your preferences, which are known by the car due to an online profile.

By: David Danks, Carnegie Mellon University

Autonomous driverless carIn 2016, self-driving cars went mainstream. Uber’s autonomous vehicles became ubiquitous in neighborhoods where I live in Pittsburgh, and briefly in San Francisco. The U.S. Department of Transportation issued new regulatory guidance for them. Countless papers and columns discussed how self-driving cars should solve ethical quandaries when things go wrong. And, unfortunately, 2016 also saw the first fatality involving an autonomous vehicle.

Autonomous technologies are rapidly spreading beyond the transportation sector, into health care, advanced cyberdefense and even autonomous weapons. In 2017, we’ll have to decide whether we can trust these technologies. That’s going to be much harder than we might expect.

Trust is complex and varied, but also a key part of our lives. We often trust technology based on predictability: I trust something if I know what it will do in a particular situation, even if I don’t know why. For example, I trust my computer because I know how it will function, including when it will break down. I stop trusting if it starts to behave differently or surprisingly.

In contrast, my trust in my wife is based on understanding her beliefs, values and personality. More generally, interpersonal trust does not involve knowing exactly what the other person will do – my wife certainly surprises me sometimes! – but rather why they act as they do. And of course, we can trust someone (or something) in both ways, if we know both what they will do and why.

I have been exploring possible bases for our trust in self-driving cars and other autonomous technology from both ethical and psychological perspectives. These are devices, so predictability might seem like the key. Because of their autonomy, however, we need to consider the importance and value – and the challenge – of learning to trust them in the way we trust other human beings.

Autonomy and predictability

We want our technologies, including self-driving cars, to behave in ways we can predict and expect. Of course, these systems can be quite sensitive to the context, including other vehicles, pedestrians, weather conditions and so forth. In general, though, we might expect that a self-driving car that is repeatedly placed in the same environment should presumably behave similarly each time. But in what sense would these highly predictable cars be autonomous, rather than merely automatic?

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Renewable liquid fuelRenewable energy is on the rise, but how we store that energy is still up for debate.

“Renewable energy is growing, but it’s intermittent,” says Grigorii Soloveichik, program director at the United States Department of Energy’s Advanced Research Projects Agency. “That means we need to store that energy and we have two ways to do that: electricity or liquid fuels.”

According to Soloveichik, electricity and batteries are sufficient for short term energy storage, but new technologies such as liquid fuels derived from renewable energy must be considered for long term storage.

During the PRiME 2016 meeting in October, Soloveichik presented a talk titled, “Development of Transformational Technologies,” where he described the advantages that carbon neutral liquid fuels have over other convention means – such as batteries – for efficient, affordable, long term storage for renewable energy sources.

Rise of renewables

In the United States, 16.9 percent of electricity generation comes from renewables – a 9.3 percent increase since 2015. Globally, climate talks such as the Paris Agreement help bolster the rise of renewable energy around the world. Soloveichik expects that growth to continue in light of the affordability of clean energy technologies and government mandates that aim at environmental protection and a reduction of the carbon footprint. However, the continued rise in renewable dependence will impact the current grid infrastructure.

“More renewables will result in more stress on the grid,” Soloveichik says. “All of these new sources are intermittent, so we need to be able to store huge amounts of energy.”

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ECS Toyota Fellowship
The Electrochemical Society with Toyota North America
2017-2018 ECS Toyota Young Investigator Fellowship
for Projects in Green Energy Technology

Proposal Submission Deadline: January 31, 2017

ECS, in partnership with the Toyota Research Institute of North America (TRINA), a division of Toyota Motor Engineering & Manufacturing North America, Inc. (TEMA), is requesting proposals from young professors and scholars pursuing innovative electrochemical research in green energy technology.

Global development of industry and technology in the 20th century, increased production of vehicles and the growing population have resulted in massive consumption of fossil fuels. Today, the automotive industry faces three challenges regarding environmental and energy issues: (1) finding a viable alternative energy source as a replacement for oil, (2) reducing CO2 emissions and (3) preventing air pollution. Although the demand for oil alternatives—such as natural gas, electricity and hydrogen—may grow, each alternative energy source has its disadvantages. Currently, oil remains the main source of automotive fuel; however, further research and development of alternative energies may bring change.

Fellowship Objectives and Content

The purpose of the ECS Toyota Young Investigator Fellowship is to encourage young professors and scholars to pursue research in green energy technology that may promote the development of next-generation vehicles capable of utilizing alternative fuels. Electrochemical research has already informed the development and improvement of innovative batteries, electrocatalysts, photovoltaics and fuel cells.

Through this fellowship, ECS and TRINA hope to see more innovative and unconventional technologies borne from electrochemical research.

The fellowship will be awarded to a minimum of one candidate annually. Winners will receive a restricted grant of no less than $50,000 to conduct the research outlined in their proposal within one year. Winners will also receive a one-year complimentary ECS membership as well as the opportunity to present and/or publish their research with ECS.

Meet previous winners.

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