By: Mike Williams, Rice University

Rice University researchers have modeled a nanoscale sandwich, the first in what they hope will become a molecular deli for materials scientists.

Their recipe puts two slices of atom-thick graphene around nanoclusters of magnesium oxide that give the super-strong, conductive material expanded optoelectronic properties.

Rice materials scientist Rouzbeh Shahsavari and his colleagues built computer simulations of the compound and found it would offer features suitable for sensitive molecular sensing, catalysis and bio-imaging. Their work could help researchers design a range of customizable hybrids of two- and three-dimensional structures with encapsulated molecules, Shahsavari said.

The research appears this month in the Royal Society of Chemistry journal Nanoscale.

The scientists were inspired by experiments elsewhere in which various molecules were encapsulated using van der Waals forces to draw components together. The Rice-led study was the first to take a theoretical approach to defining the electronic and optical properties of one of those “made” samples, two-dimensional magnesium oxide in bilayer graphene, Shahsavari said.

“We knew if there was an experiment already performed, we would have a great reference point that would make it easier to verify our computations, thus allowing more reliable expansion of our computational results to identify performance trends beyond the reach of experiments,” Shahsavari said.

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John Goodenough may be 94-years old, but he shows no sign of slowing down. Now, the co-inventor of the lithium-ion battery has developed the first all-solid-state battery cells that could result in safer, longer-lasting batteries for everything from electric cars to grid energy storage.

“Cost, safety, energy density, rates of charge and discharge and cycle life are critical for battery-driven cars to be more widely adopted,” Goodenough says in a statement. “We believe our discovery solves many of the problems that are inherent in today’s batteries.”

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ECS is sponsoring the Henry White keynote address at the 100th Canadian Chemistry Conference and Exhibition. The conference will take place in Toronto, ON, Canada, May 28 – June 1, 2017.

Canada’s premiere chemistry event takes on a special significance this year, coinciding with both the CSC meeting’s centennial and the 150th anniversary of the Confederation of Canada. CSC 2017 will feature plenary, invited and submitted lectures, jointly organized international symposia, poster sessions, panel discussions, and special events, including a closing day outreach event.

Early bird registration for the conference ends April 18, 2017. Register today.

By: Venkat Subramanian, University of Washington

This article refers to a recently published open access paper in the Journal of The Electrochemical Society, “Direct, Efficient, and Real-Time Simulation of Physics-Based Battery Models for Stand-Alone PV-Battery Microgrids.”

Tesla engineered a good electric car successfully by engineering a car design that can accommodate large battery stacks. Our hypothesis is that the current grid control method, which is a derivative of traditional grid control approaches, cannot utilize batteries efficiently.

In the current microgrid control, batteries are treated as “slaves” and are typically expected to be available to meet only the power needs. Typically, if grid optimization is done at the higher level, and then batteries are used as slaves, including models that predict fade can be used in a bi-level optimization mode (optimize grid operations and at every point in time, optimize battery operation). This way of optimization will not yield the best possible outcome for batteries.

In a recently published paper, we show that real-time simulation of the entire microgrid is possible in real-time. We wrote down all of the microgrid equations in mathematical form, including photovoltaic (PV) arrays, PV maximum power point tracking (MPPT) controllers, batteries, and power electronics, and then identified an efficient way to solve them simultaneously with battery models. The proposed approach improves the performance of the overall microgrid system, considering the batteries as collaborators on par with the entire microgrid components. It is our hope that this paper will change the current perception among the grid community.

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As we reflect on the 115th anniversary of ECS, it is also important to look towards the future and strengthen opportunities for the next generation of scientists.

In 2016, ECS provided support for student and early career scientists through:

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By: Manimaran Govindarasu, Iowa State University and Adam Hahn, Washington State University

Called the “largest interconnected machine,” the U.S. electricity grid is a complex digital and physical system crucial to life and commerce in this country. Today, it is made up of more than 7,000 power plants, 55,000 substations, 160,000 miles of high-voltage transmission lines and millions of miles of low-voltage distribution lines. This web of generators, substations and power lines is organized into three major interconnections, operated by 66 balancing authorities and 3,000 different utilities. That’s a lot of power, and many possible vulnerabilities.

The grid has been vulnerable physically for decades. Today, we are just beginning to understand the seriousness of an emerging threat to the grid’s cybersecurity. As the grid has become more dependent on computers and data-sharing, it has become more responsive to changes in power demand and better at integrating new sources of energy. But its computerized control could be abused by attackers who get into the systems.

Until 2015, the threat was hypothetical. But now we know cyberattacks can penetrate electricity grid control networks, shutting down power to large numbers of people. It happened in Ukraine in 2015 and again in 2016, and it could happen here in the U.S., too.

As researchers of grid security, we know the grid has long been designed to withstand random problems, such as equipment failures and trees falling on lines, as well as naturally occurring extreme events including storms and hurricanes. But as a new document from the National Institute of Standards and Technology suggests, we are just beginning to determine how best to protect it against cyberattacks.

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By: Ellen Finnie, In the Open

The Electrochemical Society, a small nonprofit scholarly society founded in 1902, has an important message for all of us who are concerned about access to science. Mary Yess, deputy executive director and chief content officer and publisher, could not be clearer about the increased urgency of ECS’ path: “We have got to move towards an open science environment. It has never been more important – especially in light of the recently announced ‘gag orders’ on several U.S. government agencies– to actively promote the principles of open science.” What they committed to in 2013 as an important open access initiative has become, against the current political backdrop, truly a quest to “free the science.”

ECS’s Free the Science program is designed to accelerate the ability of the research ECS publishes — for example, in sustainable clean energy, clean water, climate science, food safety, and medical care — to generate solutions to our planet’s biggest problems. It is a simple and yet powerful proposition, as ECS frames it:

“We believe that if this research were openly available to anyone who wished to read it, anywhere it the world, it would contribute to faster problem solving and technology development, accelerate the pace of scientific discovery, encourage innovation, enrich education, and even stimulate the economy.”

How this small society — which currently publishes just two journals — came to this conclusion, and how they plan to move to an entirely open access future, is, I believe, broadly instructive at a time when our political environment has only one solid state: uncertainty.

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The “queen of carbon science,” Mildred Dresselhaus, has passed away at the age of 86.

Dresselhaus was a recipient of both the Presidential Medal of Freedom and National Medal of Science, solidifying her role as a leader in the scientific community and an advocate for women in STEM.

Among her scientific contributions, Dresselhaus is perhaps most known for playing a key role in unlocking the mysteries of carbon. Her contributions to fundamental research in the electronic structure of semi-materials and initial insight into fullerenes have made an extensive impact on the scientific community.

“We lost a giant — an exceptionally creative scientist and engineer who was also a delightful human being,” MIT President L. Rafael Reif wrote in a statement. “Among her many ‘firsts,’ in 1968, Millie became the first woman at MIT to attain the rank of full, tenured professor. She was the first solo recipient of a Kavli Prize and the first woman to win the National Medal of Science in Engineering.”

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With the March for Science coming up in April, scientists are debating the pros and cons of getting political.

A new story from NPR explores the nuances of politicizing science, with some scientists supporting the upcoming march to protect science from potential governmental threats, while others believe the March for Science will damage scientists’ reputations for being unbiased.

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The Electrochemical Society was founded 115 years ago as the American Electrochemical Society. That’s based on the inaugural meeting held April 3-5, 1902 in Philadelphia, PA. Twenty papers were presented and recorded in Transactions of the American Electrochemical Society, Vol. 1, No. 1.

You could say the Society was born out of the indifference of what was known at the time as the Council of the American Chemical Society. Around this time, ACS took no action on a proposal to form an electrochemical section or division. That led Joseph Richards, the first president of the Society, to write in the inaugural Transactions:

“The day is past, we all acknowledge, when one man, even be he Newton, can know all that is to be known … the day is passing when any one society can even cover satisfactorily the whole field of any one science …”

Meeting for organization

And so in November of 1901 about 30 engineers, chemists, and scientists were invited by letter to attend “the meeting for organization” where they would create an organization:

“Its functions should be those of bringing electrochemists into personal contact with each other; of disseminating among them all the information known to, and which can be spared by, their co-workers; to stimulate original thought in these lines by mutual interchange of experience, and by papers and discussions; to stimulate electrochemical work all over the world by publishing the news of what is being done here in America.”

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