BatteryNew research from Sandia National Laboratory is moving toward advancing solid state lithium-ion battery performance in small electronics by identifying major obstacles in how lithium ions flow across battery interfaces.

The team of researchers, including ECS member Forrest Gittleson, looked at the nanoscale chemistry of solid state batteries, focusing on the area where the electrodes and electrolytes make contact.

“The underlying goal of the work is to make solid-state batteries more efficient and to improve the interfaces between different materials,” says Farid El Gabaly, coauthor of the recently published work. “In this project, all of the materials are solid; we don’t have a liquid-solid interface like in traditional lithium-ion batteries.”

According to El Gabaly, the faster the lithium can travel from one electrode to the other, the more efficient the batteries could be.

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Carbon dioxide Scientists have found a way to make their asphalt-based sorbents better at capturing carbon dioxide from gas wells: Adding water.

The lab of chemist James Tour, a chair in chemistry as well as a professor of computer science and of materials science and nanoengineering at Rice University, discovered that treating grains of inexpensive Gilsonite asphalt with water allows the material to adsorb more than two times its weight in the greenhouse gas. The treated asphalt selects carbon dioxide over valuable methane at a ratio of more than 200-to-1.

The material performs well at ambient temperatures and under the pressures typically found at wellheads. When the pressure abates, the material releases the carbon dioxide, which can then be stored, sold for other industrial uses, or pumped back downhole.

Natural gas at the wellhead typically contains between 3 and 7 percent carbon dioxide, but at some locations may contain up to 70 percent. Oil and gas producers traditionally use one of two strategies to sequester carbon dioxide: physically through the use of membranes or solid sorbents like zeolites or porous carbons, or chemically through filtering with liquid amine, a derivative of ammonia.

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Transforming Carbon Dioxide

Carbon dioxideCarbon dioxide accounts for over 80 percent of all greenhouse gas emissions. For many, carbon dioxide emissions account for significant environmental issues, but for researchers like Haotian Wang of Harvard University, carbon dioxide could be the perfect raw material.

According to a new study, Wang and his team are well on the way to developing a system that uses renewable electricity to electrochemically transform carbon dioxide into carbon monoxide. The carbon monoxide could then be used in a host of industrial processes, such as plastics production, creating hydrocarbon products, or as a fuel itself.

This from Harvard University:

The energy conversion efficiency from sunlight to CO can be as high as 12.7%, more than one order of magnitude higher than natural photosynthesis.

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Carbon NanotubesThe introduction of purified carbon nanotubes appears to have a beneficial effect on the early growth of wheatgrass, according to scientists. But in the presence of contaminants, those same nanotubes could do great harm.

The Rice University lab of chemist Andrew Barron grew wheatgrass in a hydroponic garden to test the potential toxicity of nanoparticles on the plant. To their surprise, they found one type of particle dispersed in water helped the plant grow bigger and faster.

They suspect the results spring from nanotubes’ natural hydrophobic (water-avoiding) nature that in one experiment apparently facilitated the plants’ enhanced uptake of water.

The lab mounted the small-scale study with the knowledge that the industrial production of nanotubes will inevitably lead to their wider dispersal in the environment. The study cites rapid growth in the market for nanoparticles in drugs, cosmetics, fabrics, water filters, and military weapons, with thousands of tons produced annually.

Despite their widespread use, Barron says few researchers have looked at the impact of environmental nanoparticles—whether natural or human-made—on plant growth.

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Researchers have developed a prototype device that mimics natural photosynthesis to produce ethylene gas using only sunlight, water, and carbon dioxide.

The novel method, which produces ethylene at room temperature and pressure using benign chemicals, could be scaled up to provide a more eco-friendly and sustainable alternative to the current method of ethylene production.

Ethylene, which is the building block of polyethylene, is an important chemical feedstock produced in large quantities for manufacturing plastics, rubber, and fibers. More than 170 million tons of ethylene were produced worldwide in 2015 alone, and the global demand is expected to exceed 220 million tons by 2020.

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BiofuelNew research stitches together the best parts of several different bacteria to synthesize a new biofuel product that matches current engines better than previously produced biofuels.

“My lab is interested in developing microbial biosynthetic processes to make biofuels, chemicals, and materials with tailored structures and properties,” says Fuzhong Zhang, associate professor at the School of Engineering & Applied Science at Washington University in St. Louis. “Previously, we engineered E.coli to produce a precursor compound that leads to the production of advanced biofuels. In this work, we took the next step toward the actual manufacture.”

Zhang’s research focuses on engineering metabolic pathways that, when optimized, allow the bacteria to act as a biofuel generator. In its latest findings, recently published in Biotechnology for Biofuels, Zhang’s lab used the best bits of several other species—including a well-known pathogen—to enable E. coli to produce branched, long-chain fatty alcohol (BLFL), a substance that can be used as a freeze-resistant, liquid biofuel.

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OpenCon Q&A: Changing Culture

We are podcasting the question and answer section of the live broadcast ECS did of the OpenCon satellite event held at the 232nd ECS Meeting in October of 2017.

ECS OpenCon was a community event aimed at creating a culture of change in how research is designed, shared, discussed, and disseminated, with the ultimate goal of making scientific progress faster.

ECS was the first scholarly society to host an OpenCon satellite event.

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2017 Canada Section Awards

Canadian flagThe ECS Canada Section recently awarded Leah Ellis and Yurij Mozharivskyj the 2017 Canada Section Student Award and W. Lash Miller Award, respectively.

Canada Section Student Award

The Canada Section Student Award was established in 1987 to recognize promising young scientists and engineers in the field of electrochemical power sources. The 2017 award went to Leah Ellis, a PhD candidate at Dalhousie University working in lithium-ion battery research.

“This ECS Canada Section Student Award is very prestigious,” Ellis said. “Looking at the list of past award winners, I feel very honored and humbled to be included in this list. The award is very inspiring to me, and I hope to live up to its reputation.”

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In a recent interview, ReasonsTV sat down with PLOS co-founder Michael Eisen to discuss open access, the academic publishing monopoly, and ways to democratize scientific progress.

PS: ECS’s Free the Science initiative is a move toward a future that embraces open science to further advance research in our field. This is a long-term vision for transformative change in the traditional models of communicating scholarly research.

Other ECS programs that advance the shift to open science include the upcoming launch of ECSarXiv, a preprint server through a partnership with the Center for Open Science, enhanced research dissemination with Research4Life, ECS OpenCon, and expanding our publications to include more research in data sciences.

Poplar treeNew research indicates that poplar trees could be an economically viable biofuel material.

In the quest to produce affordable biofuels, poplars are one of the Pacific Northwest’s best bets—the trees are abundant, fast-growing, adaptable to many terrains, and their wood can become substances used in biofuel and high-value chemicals that we rely on in our daily lives.

But even as researchers test poplars’ potential to morph into everything from ethanol to chemicals in cosmetics and detergents, a commercial-scale processing plant for poplars has yet to be achieved. This is mainly because production costs still are not competitive with the current price of oil.

Now, a team of researchers is trying to make poplar a viable competitor by testing the production of younger poplar trees that could be harvested more frequently—after only two or three years—instead of the usual 10- to 20-year cycle.

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