Image: NYU’s Jerschow Lab

Researchers from New York University have developed a new technique to give a highly detailed, 3D look inside a lithium-ion battery.

“One particular challenge we wanted to solve was to make the measurements 3D and sufficiently fast, so that they could be done during the battery charging cycle,” explains Alexej Jerschow, co-author of the study that details the development. “This was made possible by using intrinsic amplification processes, which allow one to measure small features within the cell to diagnose common battery failure mechanisms. We believe these methods could become important techniques for the development of better batteries.”

The look that the researchers offer gives new insight to dendrites – the deposits that build up inside a Li-ion battery that can affect performance and safety. To do this, the team used MRI technology to focus the image and took an additional step to improve image quality.

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One year ago Tesla Motors announced plans to build its Gigafactory to produce huge numbers of batteries, giving life to the old saying, “if you want something done right, do it yourself.”

By making electric car batteries that Tesla used to buy from others, CEO Elon Musk adopted a strategy made famous by Henry Ford – build a vertically integrated company that controls the many stages of production. By integrating “backward” into its supply chain, Musk is betting Tesla can improve the performance and lower the costs of batteries for its vehicles.

Now, Musk wants Tesla to acquire SolarCity for similar reasons, but with a slightly different twist.

SolarCity is one of the largest installers of solar photovoltaic panels, with some 300,000 residential, commercial and industrial customers in 27 states. The proposed merger with SolarCity would vertically integrate Tesla forward, as opposed to backward, into the supply chain. That is, when people come to Tesla stores to buy a vehicle, they will be able to arrange installation of solar panels – and potentially home batteries – at the same time.

This latest move would bring Tesla one step closer to being the fully integrated provider of sustainable energy solutions for the masses that Elon Musk envisions. But does it make business sense?

The real issue in my mind comes down to batteries and innovation.

Creating demand and scale

Although installing batteries is not a big part of SolarCity’s current business, the company is a potentially large consumer of Tesla’s batteries from the Gigafactory. Tesla makes Powerwall batteries for homes and larger Powerpack systems for commercial and industrial customers.

Any increase in the flow of batteries through the factory gives Tesla better economies of scale and potential for innovation. Innovation comes with the accumulated experience gained from building a key component of its electric vehicles as well as Tesla’s energy storage systems. As the company manufactures more batteries, it will find ways to innovate around battery design and production.

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Image: CC0

Last week, Samsung ordered a global recall of its Galaxy Note 7 phones after investigations into claims of exploding devices revealed faulty lithium-ion batteries. Now, the FAA is strongly urging passengers to forge bringing the device on airliners due to safety risks.

Earlier this year, we spoke to ECS member K.M. Abraham about lithium-ion battery devices and safety concerns associated with them.

“It is safe to say that these well-publicized hazardous events are rooted in the uncontrolled release of the large amount of energy stored in Li-ion batteries as a result of manufacturing defects, inferior active and inactive materials used to build cells and battery packs, substandard manufacturing and quality control practices by a small fraction of cell manufacturers, and user abuses of overcharge and over-discharge, short-circuit, external thermal shocks and violent mechanical impacts,” Abraham said. “Safety hazards of Li-ion batteries occur when the fundamental principle of controlled release of energy on which battery technology is based is compromised by materials and manufacturing defects and operational abuses.”

Read Abraham’s full paper on Li-ion safety and building better batteries.

Currently, electric vehicles depend on a complex interplay of batteries and supercapacitors to get you where you’re going. But a recently published paper, co-authored by ECS Fellow Hector Abruna, details the development of a new material that can take away some of the complexity of EVs.

“Our material combines the best of both worlds — the ability to store large amounts of electrical energy or charge, like a battery, and the ability to charge and discharge rapidly, like a supercapacitor,” says William Dichtel, lead author of the study.

This from Northwestern University:

[The research team] combined a COF — a strong, stiff polymer with an abundance of tiny pores suitable for storing energy — with a very conductive material to create the first modified redox-active COF that closes the gap with other older porous carbon-based electrodes.

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New research shows another step forward in the goal of developing energy storage systems robust enough to store such intermittent sources as wind and solar on a large-scale.

Their work explores the opportunities in solid oxide cells (SOCs), which the group believes to be one of the best prospects in energy storage due to their high efficiency and wide range of scales.

ECS member John Irvine and his team from the University of St. Andrews have set out to overcome traditional barriers in this technology, developing a new method of electrochemical switching to simplify the manufacturing of the electrodes needed to deliver high, long-lasting energy activity.

This from the University of St. Andrews:

The results demonstrate a new way to produce highly active and stable nanostructures – by growing electrode nanoarchitectures under operational conditions. This opens exciting new possibilities for activating or reinvigorating fuel cells during operation.

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The world’s next energy revolution is looming nearer.

In order to bolster this transformation, the U.S. Department of Energy has been funding 75 projects in the energy technology field, enabling cutting-edge research into energy conversion and storage. This effort is part of the DOE’s goal to “decarbonize” the U.S. energy infrastructure by the middle of the country.

One of the most promising projects funded by the DOE is led by ECS member Michael Aziz, where he and his team from Harvard are addressing challenges in grid energy storage.

Energy storage has become one of the largest barriers in the widespread implementation of renewables. By offering a cost-effective, efficient answer to energy storage, the issues of intermittency in power sources such as wind and solar could be answered.

Aziz and his team are addressing issues in energy storage with the development of a flow battery based on inexpensive organic molecules in a water-based electrolyte. The team is focusing on using quinone molecules, which can be found in such plant sources as rhubarb or even oil waste. The quinone molecules allow energy to be stored in a water-based solution at room temperature.

Aziz recently discussed some of his work in quinon-bromide flow batteries as part of the Journal of The Electrochemical Society Focus Issue on Redox Flow Batteries-Reversible Fuel Cells.

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Electric vehicles have become more visible in the automobile market over the past few years, but many potential buyers still cite one thing as a major deterrent in going electric: range anxiety.

Range anxiety is a term many use to describe the fear of an EV’s battery running out of juice while driving, leaving them stranded away from a charging station.

However, a new study published by a team from MIT and the Santa Fe Institute looked at data in order to come to a conclusion that range anxiety is not something that most drivers really need to worry about.

Overcoming range anxiety

“What we found was that 87 percent of vehicles on the road could be replaced by a low cost electric vehicle available today, even if there’s no possibility to recharge during the day,” senior author of the study, Jessika Trancik, told The Washington Post.

As technology progresses, EVs continue to have a leg up on traditional gasoline-powered vehicles. In 2015, battery prices for EVs fell by 35 percent. By 2040, experts predict that long-range EV prices will be less than $22,000. Additionally, an expected 35 percent of all new cars world-wide are expected to come with a plug.

Even as the technology progresses, sociological barriers such as range anxiety remain as a factor that stands in the way of a full market boom of EVs.

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Image: SLAC National Accelerator Laboratory

A Stanford University-led team recently published research detailing how particles charge and discharge at the nanoscale, giving new insight into the fundamental functioning of batteries and opening doors for the development of better rechargeables.

This new insight into the electrochemical action that powers Li-ion batteries provides powerful knowledge into the building blocks of batteries.

“It gives us fundamental insights into how batteries work,” says Jongwoo Lim, a co-author of the study. “Previously, most studies investigated the average behavior of the whole battery. Now, we can see and understand how individual battery particles charge and discharge.”

At the heart of every Li-ion battery lies the charge/discharge process. In theory, the ions in the process insert uniformly across the surface of the particles. However, that never happens in practice. Instead, the ions get unevenly distributed, leaving inconsistencies that lead to mechanical stresses and eventually shortened battery life. One way to develop batteries with longer life spans is to understand why these phenomena happens and how to prevent it at the nanoscale.

The recently published research uses x-rays and cutting-edge microscopes to look at this process in real time.

“The phenomenon revealed by this technique, I thought would never be visualized in my lifetime. It’s quite game-changing in the battery field,” says Martin Bazant, co-author of the study.

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Image: ANL/Flickr

A new open access paper published in the Journal of The Electrochemical Society entitled, “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment,” finds a new cathode coating for li-ion batteries that could extend the technology’s lifespan.

According to Green Car Congress, the dissolution of transition metals is a major contributor to a li-ion battery’s expedited aging and degradation. However, this new study published in JES by ECS members David Snydacker, Muratahan Aykol, Scott Kirklin, and Christopher Wolverton from Northwestern University makes the case for a new, promising candidate that can act as a stable coating and limit the dissolution of transition metals into the lion electrolyte. That candidate is Li₃PO₄.

This from “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment”:

There are several distinct categories of strategies for limiting TM dissolution from the cathode. Electrolytes can be tailored to reduce reactivity with the cathode. Cathode materials can be doped to control the oxidation states of transition metals. This doping can be applied to the entire cathode particle or just near the surface. Cathode materials can also be covered with surface coatings to limit TM dissolution. Surface coatings can perform a variety of functions for different cathode materials. In this work, we evaluate the ability of coating materials to contain TMs in the cathode and thereby prevent TM dissolution into the electrolyte.

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Image: MIT

New lithium-oxygen battery technology proposed by researchers from MIT, Argonne National Laboratory, and Peaking University, promises a scalable, cheap, and safe option in energy storage.

There is immense promise for lithium-oxygen batteries in such applications as electric cars and portable electronics. In fact, they are between five and 15 times more efficient than lithium-ion batteries in transportation applications due to their high energy output potential in proportion to their weight.

But there have been complications in developing and especially implementing these batteries in the marketplace. Primarily, they’ve been known to waste energy and degrade quickly.

But this new study, co-authored by ECS member and past IMLB chair Khalil Amine, states that the theoretical potential for lithium-oxygen batteries could be met while overcoming some of the biggest barriers prohibiting the technology.

Once of the primary focuses of the group was overcoming the mismatch in voltages that happens in charging and discharging the battery. Because the output voltage is more than 1.2 volts lower that that used to charge, there is typically a significant power loss.

“You waste 30 percent of the electrical energy as heat in charging,” says Ju Li, professor at MIT and co-author of the paper. “It can actually burn if you charge it too fast.”

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