When it comes to energy storage, hydrogen is becoming more and more promising. From hydrogen fuel cell vehicles to the “artificial leaf” to the transformation of waste heat into hydrogen, researchers are looking to hydrogen for answers to the growing demand for energy storage.

At the Lawrence Livermore National Laboratory (LLNL), researchers are using hydrogen to make lithium ion batteries operate longer and have faster transport rates.

In a response to the need for higher performance batteries, the researchers began by looking for a way to achieve better capacity, voltage, and energy density. Those qualities are primarily determined by the binding between lithium ions and electrode material. Small changes to the structure and chemistry of the electrode can mean big things for the qualities of the lithium ion battery.

The research team from LLNL discovered that by subtly changing the electrode, treating it with hydrogen, lithium ion batteries could have higher capacities and faster transport levels.

“These findings provide qualitative insights in helping the design of graphene-based materials for high-power electrodes,” said Morris Wang, an LLNL materials scientist and co-author of the paper.

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With the transportation sectors of industrialized countries on the rise and greenhouse gas emissions at an all-time high, many scientists and engineers are searching for the next-generation of transportation. From hybrid to electric to hydrogen, alternative energy sources for vehicles are being explored and tested throughout the scientific community. Now, many are wondering which technology will win in the race between battery- and hydrogen-powered cars.

A recent open access paper published in the Journal of The Electrochemical Society (JES) explores this topic. Authors Hubert A. Gasteiger, Jens-Peter Suchsland, and Oliver Gröger have outlined the technological barriers for next-generation vehicles in “Review—Electromobility: Batteries or Fuel Cells?” This paper comes as part of the recent JES Collection of Invited Battery Review Papers.

The majority of today’s vehicles depend on petroleum-based products in internal combustion engines to operate. The burning of these fuels results in the emission of greenhouse gasses. The majority of these transportation sector greenhouse gas emissions do not come from large modes of transportation such as aircrafts or ships—but are primarily produced by cars, trucks, and SUVs.

In the recently published review, the authors describe the possibilities of extended range electric vehicles, the challenges in hydrogen fuel cell vehicles, and the potential for new materials to be used in these applications.

Read this open access paper and read the rest of the JES Collection of Invited Battery Review Papers.

The spotlight is on the Brno Student Chapter from the Czech Republic! The Brno Student Chapter was established in 2006. The focus of their activities is on batteries, electrochemical conversion and the storage research field.

On September 3, 2015, members of the Brno Chapter presented at the 16^th International Conference on Advanced Batteries, Accumulators and Fuel Cells, also known as ABAF. Proceedings of this meeting will be published in an edition of ECS Transactions. In addition, four members have submitted dissertation theses this year, which are scheduled to be presented and defended early 2016. Great job, Brno!

Want your student chapter in the spotlight? Send an email to beth.fisher@electrochem.org to tell us what makes your chapter stand out!

On the path to building better batteries, researchers have been choosing silicon as their material of choice to increase life-cycle and energy density. Silicon is favored among researchers because its anodes have the ability to store up to ten times the amount of lithium ions than conventional graphite electrodes. However, silicon is a rather rigid material, which makes it difficult for the battery to withstand volume changes during charge and discharge cycles.

This from Georgia Tech:

Using a combination of experimental and simulation techniques, researchers from the Georgia Institute of Technology and three other research organizations have reported surprisingly high damage tolerance in electrochemically-lithiated silicon materials. The work suggests that all-silicon anodes may be commercially viable if battery charge levels are kept high enough to maintain the material in its ductile state.

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Batteries are a critical part of our everyday lives. From phones to laptops to cars to grid energy storage—batteries are essential to many devices. Lithium ion batteries have taken the lead in battery technology, with lithium iron phosphate batteries (LFP) performing particularly well. While it was known that LFP batteries could charge quickly and withstand many factors, the reasons for this were unknown until know.

A team of researchers from the Paul Scherrer Institute and Toyota Central R&D Labs has discovered why LFP batteries can be recharged so rapidly. The team is comprised of ECS member Tsuyoshi Sasaki, past members Michael Hess and Petr Novak, and Journal of The Electrochemical Society (JES) published author Claire Villevieille.

(PS: Check out their past paper, “Surface/Interface Study on Full xLi₂MnO₃·(1 − x)LiMO₂ (M = Ni, Mn, Co)/Graphite Cells.”)

This from Paul Scherrer Institute:

The reason: the step-like concentration gradient gives way to a gentle, ramp-like progression of the lithium concentration. This is because, at higher voltages, the lithium ions involved in the charging process are distributed across the volume of the electrode particles for brief moments as opposed to being herded together in a thin layer boundary. As a result, the lithium can be set in motion more easily during charging, without the need for more energy to be added to negotiate the layer boundary.

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Earlier this year, we looked at the Israeli start-up company StoreDot’s innovative research in battery technology that could allow a smartphone battery to charge in just 30 seconds.

Now, the same company is taking that same technology and applying it to electric vehicles.

The company is claiming to have tweaked their technology to fully charge an electric car in just five minutes.

According to StoreDot, an array of 7,000 cells could enable electric vehicles to travel up to 300 mile on just a five minute charge.

This from Ecomento:

StoreDot believes it can speed up charging by creating a new variant of the industry-standard lithium-ion chemistry. It uses nanotechnology to make new organic materials that researchers claim have lower resistance than the materials used in current lithium-ion cells. That means electricity can flow through the battery more easily.

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EJ Taylor, ECS Treasurer and Chief Technical Officer at Faraday Technology, recently ran across this article from The Economist discussing an accidental discovery that could yield big results.

Materials scientists Wang Changan of Tsinghua University and Li Ju of MIT may have unintentionally found the answer to developing a battery that can last up to four times longer than the current generation.

Initially, the scientists were simply researching nanoparticles made of aluminum. While these tiny particles are good conductors of electricity, they become less efficient when exposed to air. When air hits these tiny particles, a coating of an oxide film begins to develop, greatly affecting the performance. The research the two scientists were working on was not to create a better battery, but rather to eliminate the oxide that coats the particles.

This from The Economist:

Their method was to soak the particles in a mixture of sulphuric acid and titanium oxysulphate. This replaces the aluminium oxide with titanium oxide, which is more conductive. However, they accidentally left one batch of particles in the acidic mixture for several hours longer than they meant to. As a result, though shells of titanium dioxide did form on them as expected, acid had time to leak through these shells and dissolve away some of the aluminium within. The consequence was nanoparticles that consisted of a titanium dioxide outer layer surrounding a loose kernel of aluminium.

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Potatoes are great in many forms: mashed, baked, roasted, electrochemical energy source… Most people have seen or experienced the potato battery experiment in a chemistry class, but BatteryBox is taking this exercise to a whole new level.

As you know, one or two potatoes produce enough energy to power a small digital clock. But how much energy would 110 pound of potatoes produce? Enough to charge a smartphone?

For this experiment, the team at BatteryBox cut up and boiled the potatoes to increase the energy transfer. This allows for the harnessing of the full power of the potato.

Essentially, the team combined the 110 pounds of potatoes to create a galvanic cell.

PS: Check out some more practical applications of electrochemical energy at the 228th ECS Meeting.

A new development out of the Ulsan National Institute of Science and Technology (UNIST) has yielded a new technique that could make it possible to print batteries on any surface.

With recent interests in flexible electronics—such as bendable screen displays—researchers globally have been investing research efforts into developing printable functional materials for both electronic and energy applications. With this, many researchers predict the future of the li-ion battery as one with far less size and shape restrictions, having the ability to be printed in its entirety anywhere.

The research team from UNIST, led by ECS member Sang-Young Lee, is setting that prediction on the track to reality. Their new paper published in the journal Nano Letters details the printable li-ion battery that can exist on almost any surface.

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Lithium-air batteries are—in theory—an extremely attractive alternative for affordable, efficient energy storage for electric vehicles. However, as researchers explore this technology, they are met with many critical challenges. If researchers can overcome these challenges, there is a great likelihood that the lithium-air battery will surpass the energy density of today’s lithium-ion battery.

Researchers from Carnegie Mellon University and the University of California, Berkley feel like they may have part of the answer to this critical challenge, which could propel the practicality of the lithium-air battery. The team, which included researchers from Bryan McCloskey and Venkat Viswanathan‘s laboratories, has found a way to both increase the capacity while preserving the recharge ability of the lithium-air battery by blending different types within the battery’s electrolytes.

“The electrolytes used in batteries are just like Gatorade electrolytes,” says Venkat Viswanathan, assistant professor of mechanical engineering at Carnegie Mellon. “Every electrolyte has a solvent and a salt. So if you take Gatorade, the solvent would be water and the salt would be something like sodium chloride, for instance. However, in a lithium air battery, the solvent is dimethoxyethane and the salt is something like lithium hexafluorophosphate.”

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