On the path to building better batteries, researchers have been choosing silicon as their material of choice to increase life-cycle and energy density. Silicon is favored among researchers because its anodes have the ability to store up to ten times the amount of lithium ions than conventional graphite electrodes. However, silicon is a rather rigid material, which makes it difficult for the battery to withstand volume changes during charge and discharge cycles.
This from Georgia Tech:
Using a combination of experimental and simulation techniques, researchers from the Georgia Institute of Technology and three other research organizations have reported surprisingly high damage tolerance in electrochemically-lithiated silicon materials. The work suggests that all-silicon anodes may be commercially viable if battery charge levels are kept high enough to maintain the material in its ductile state.
Batteries are a critical part of our everyday lives. From phones to laptops to cars to grid energy storage—batteries are essential to many devices. Lithium ion batteries have taken the lead in battery technology, with lithium iron phosphate batteries (LFP) performing particularly well. While it was known that LFP batteries could charge quickly and withstand many factors, the reasons for this were unknown until know.
A team of researchers from the Paul Scherrer Institute and Toyota Central R&D Labs has discovered why LFP batteries can be recharged so rapidly. The team is comprised of ECS member Tsuyoshi Sasaki, past members Michael Hess and Petr Novak, and Journal of The Electrochemical Society (JES) published author Claire Villevieille.
The reason: the step-like concentration gradient gives way to a gentle, ramp-like progression of the lithium concentration. This is because, at higher voltages, the lithium ions involved in the charging process are distributed across the volume of the electrode particles for brief moments as opposed to being herded together in a thin layer boundary. As a result, the lithium can be set in motion more easily during charging, without the need for more energy to be added to negotiate the layer boundary.
Earlier this year, we looked at the Israeli start-up company StoreDot’s innovative research in battery technology that could allow a smartphone battery to charge in just 30 seconds.
The company is claiming to have tweaked their technology to fully charge an electric car in just five minutes.
According to StoreDot, an array of 7,000 cells could enable electric vehicles to travel up to 300 mile on just a five minute charge.
This from Ecomento:
StoreDot believes it can speed up charging by creating a new variant of the industry-standard lithium-ion chemistry. It uses nanotechnology to make new organic materials that researchers claim have lower resistance than the materials used in current lithium-ion cells. That means electricity can flow through the battery more easily.
EJ Taylor, ECS Treasurer and Chief Technical Officer at Faraday Technology, recently ran across this article from The Economist discussing an accidental discovery that could yield big results.
Materials scientists Wang Changan of Tsinghua University and Li Ju of MIT may have unintentionally found the answer to developing a battery that can last up to four times longer than the current generation.
Initially, the scientists were simply researching nanoparticles made of aluminum. While these tiny particles are good conductors of electricity, they become less efficient when exposed to air. When air hits these tiny particles, a coating of an oxide film begins to develop, greatly affecting the performance. The research the two scientists were working on was not to create a better battery, but rather to eliminate the oxide that coats the particles.
This from The Economist:
Their method was to soak the particles in a mixture of sulphuric acid and titanium oxysulphate. This replaces the aluminium oxide with titanium oxide, which is more conductive. However, they accidentally left one batch of particles in the acidic mixture for several hours longer than they meant to. As a result, though shells of titanium dioxide did form on them as expected, acid had time to leak through these shells and dissolve away some of the aluminium within. The consequence was nanoparticles that consisted of a titanium dioxide outer layer surrounding a loose kernel of aluminium.
Potatoes are great in many forms: mashed, baked, roasted, electrochemical energy source… Most people have seen or experienced the potato battery experiment in a chemistry class, but BatteryBox is taking this exercise to a whole new level.
As you know, one or two potatoes produce enough energy to power a small digital clock. But how much energy would 110 pound of potatoes produce? Enough to charge a smartphone?
For this experiment, the team at BatteryBox cut up and boiled the potatoes to increase the energy transfer. This allows for the harnessing of the full power of the potato.
Essentially, the team combined the 110 pounds of potatoes to create a galvanic cell.
PS: Check out some more practical applications of electrochemical energy at the 228th ECS Meeting.
The batteries have the ability to be integrated into the surface of the objects, making it seem like seem like there is no battery at all.
A new development out of the Ulsan National Institute of Science and Technology (UNIST) has yielded a new technique that could make it possible to print batteries on any surface.
With recent interests in flexible electronics—such as bendable screen displays—researchers globally have been investing research efforts into developing printable functional materials for both electronic and energy applications. With this, many researchers predict the future of the li-ion battery as one with far less size and shape restrictions, having the ability to be printed in its entirety anywhere.
The research team from UNIST, led by ECS member Sang-Young Lee, is setting that prediction on the track to reality. Their new paper published in the journal Nano Lettersdetails the printable li-ion battery that can exist on almost any surface.
Lithium-air batteries are—in theory—an extremely attractive alternative for affordable, efficient energy storage for electric vehicles. However, as researchers explore this technology, they are met with many critical challenges. If researchers can overcome these challenges, there is a great likelihood that the lithium-air battery will surpass the energy density of today’s lithium-ion battery.
Researchers from Carnegie Mellon University and the University of California, Berkley feel like they may have part of the answer to this critical challenge, which could propel the practicality of the lithium-air battery. The team, which included researchers from Bryan McCloskey and Venkat Viswanathan‘s laboratories, has found a way to both increase the capacity while preserving the recharge ability of the lithium-air battery by blending different types within the battery’s electrolytes.
“The electrolytes used in batteries are just like Gatorade electrolytes,” says Venkat Viswanathan, assistant professor of mechanical engineering at Carnegie Mellon. “Every electrolyte has a solvent and a salt. So if you take Gatorade, the solvent would be water and the salt would be something like sodium chloride, for instance. However, in a lithium air battery, the solvent is dimethoxyethane and the salt is something like lithium hexafluorophosphate.”
Printing technologies in an atmospheric environment offer the potential for low-cost and materials-efficient alternatives for manufacturing electronics and energy devices such as luminescent displays, thin-film transistors, sensors, thin-film photovoltaics, fuel cells, capacitors, and batteries. Significant progress has been made in the area of printable functional organic and inorganic materials including conductors, semiconductors, and dielectric and luminescent materials.
These new printable functional materials have and will continue to enable exciting advances in printed electronics and energy devices. Some examples are printed amorphous oxide semiconductors, organic conductors and semiconductors, inorganic semiconductor nanomaterials, silicon, chalcogenide semiconductors, ceramics, metals, intercalation compounds, and carbon-based materials.
A special focus issue of the ECS Journal of Solid State Science and Technology was created about the publication of state-of-the-art efforts that address a variety of approaches to printable functional materials and device. This focus issue, consisting of a total of 15 papers, includes both invited and contributed papers reflecting recent achievements in printable functional materials and devices.
The topics of these papers span several key ECS technical areas, including batteries, sensors, fuel cells, carbon nanostructures and devices, electronic and photonic devices, and display materials, devices, and processing. The overall collection of this focus issue covers an impressive scope from fundamental science and engineering of printing process, ink chemistry and ink conversion processes, printed devices, and characterizations to the future outlook for printable functional materials and devices.
The video below demonstrates Printed Metal Oxide Thin-Film Transistors by J. Gorecki, K. Eyerly, C.-H. Choi, and C.-H. Chang, School of Chemical, Biological and Environmental Engineering, Oregon State University.
Researchers believe that as work continues in relation to this study, battery technology will accelerate forward. Image: Stony Brook University
A collaborative group of six researchers from Stony Brook University and Brookhaven National Laboratory are using pioneering x-ray techniques to build a better and more efficient battery.
The researchers—four of whom are active ECS members, including Esther Takeuchi, Kenneth Takeuchi, Amy Marschilok, and Kevin Kirshenbaum—have recently published their internal mapping of atomic transformations of the highly conductive silver matrix formation within lithium-based batteries in the journal Science.
(PS: You can find more of these scientists’ cutting-edge research by attending the 228th ECS Meeting in Phoenix, where they will be giving presentations. Also, Esther Takeuchi will be giving a talk at this years Electrochemical Energy Summit.)
This from Stony Brook University:
In a promising lithium-based battery, the formation of a silver matrix transforms a material otherwise plagued by low conductivity. To optimize these multi-metallic batteries—and enhance the flow of electricity—scientists need a way to see where, when, and how these silver, nanoscale “bridges” emerge. In the research paper, the Stony Brook and Brookhaven Lab team successfully mapped this changing atomic architecture and revealed its link to the battery’s rate of discharge. The study shows that a slow discharge rate early in the battery’s life creates a more uniform and expansive conductive network, suggesting new design approaches and optimization techniques.
The new structure has high mobility of Na+ ions and a robust framework. Image: Nature Communications
With the demand for hand-held electronics at an all-time high, the costs of the materials used to make them are also rising. That includes materials used to make lithium batteries, which is a cause for concern when projecting the development of large-scale grid storage.
In order to find an alternative solution to the high material costs connected with lithium batteries, the researchers at the Australian Nuclear Science and Technology Organisation (ANSTO) and the Institute of Physics at the Chinese Academy of Science in Beijing have begun focusing their attention on sodium-ion batteries.
The science around sodium-ion batteries dates back to the 1980s, but the technology never took off due to resulting low energy densities and short life cycles.
However, the new research looks to combat those issues by improving the properties of a class of electrode materials by manipulating their electron structure in the sodium-ion battery.
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