There is no short supply of bourbon in Kentucky. But like many products, the distillation of the state’s unofficial beverage produces a sludgy waste known as bourbon stillage. The question for one researcher from the University of Kentucky’s Center for Applied Energy Research was how to repurpose that waste into something with tremendous potential.

To answer that question, ECS member Stephen Lipka and his Electrochemical Power Sources group set out to transform the bourbon stillage through a process called hydrothermal carbonization, where the liquid waste gets a dose of water and heat to produce green materials.

(MORE: See more of Lipka’s work in the ECS Digital Library.)

“In Kentucky, we have this stillage that contains a lot of sugars and carbohydrates so we tried it and it works beautifully,” says Lipka. “We take these [green materials] and we then do additional post-processing to convert it into useful materials that can be used for batteries.”

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New research from the University of Washington is opening another avenue in the quest for better batteries and fuel cells. But this research is not a breakthrough in efficiency or longevity, rather a tool to more closely analyze how batteries work.

While we’ve come a long way from the voltaic pile of the 1800s, there is still much work to be done in the field of energy storage to meet modern day needs. In a society that is looking for ways to power electric vehicles and implement large scale grid energy storage for renewables, batteries and fuel cells have never been more important.

A research team from the University of Washington – including ECS members Stuart B. Adler and Timothy C. Geary – believes that these improvements will likely have to happen at the nanoscale. But in order to improve batteries and fuel cells at that microscopic level, we must first understand and see how they function.

[MORE: Read the full journal article.]

The newly developed probe offers a window for researchers to understand how batteries and fuel cells really work.

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In the field of batteries, lithium is king. But a recent development from scientists at the Toyota Research Institute of North America (TRINA) may introduce a new competitor to the field.

The researchers have recently developed the first non-corrosive electrolyte for a rechargeable magnesium battery, which could open the door to better batteries for everything from cars to cell phones.

“When magnesium batteries become a reality, they’ll be much smaller than current lithium-ion,” says Rana Mohtadi, principal scientist and ECS patron member through TRINA. “They’ll also be cheaper and much safer.”

Magnesium has long been looked at as a possible alternative to lithium due to its high energy density. However, these batteries have not seen much attention in research and development due to the previously non-existent electrolyte. Now that the electrode has been developed, the researchers believe they will be able to demonstrate the value of this system.

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While you may be unfamiliar with Khalil Amine, he has made an immense impact in your life if you happen to use batteries in any way.

As a researcher with a vision of where the science can be applied in the market, Amine has been monumental in developing and moving some of the biggest breakthroughs in battery technology from the lab to the marketplace.

Amine is currently head of the Technology Development Group in the Battery Technology Department at Argonne National Laboratory. From 1998-2008 he was the most cited scientist in the world in the field of battery technology.

He is the chair of the organizing committee for the 18th International Meeting on Lithium Batteries being held this June in Chicago.

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Researchers at the University of California, Irvine may have just developed the ever-lasting battery.

A recent study, published in ACS Energy Letters, details a nanowire-based battery material that can be recharged hundreds of thousands of times – making more realistic the idea of a battery that would never need to be replaced.

Potential applications for the battery range from computers and smartphones to cars and spacecrafts.

Highly-conductive nanowires have always been thought appropriate for battery design, but were held back by the fact that their fragility causes them to breakdown after multiple charging cycles. By coating a gold nanowire in a manganese dioxide shell and encasing the assembly in an electrolyte, the researchers have turn the frail structure into something that has almost infinite recharging capabilities.

Mya Le Thai, a doctoral candidate, led the charge on the research – cycling the tested electrode up to 200,000 times over a three month period without loss of capacity or damage to the nanowire.

“Mya was playing around, and she coated this whole thing with a very thin gel layer and started to cycle it. She discovered that just by using this gel, she could cycle it hundreds of thousands of times without losing any capacity,” said Reginald M. Penner, chair of UC Irvine’s chemistry department and ECS member. “That was crazy, because these things typically die in dramatic fashion after 5,000 or 6,000 or 7,000 cycles at most.”

Thai believes that this study shows that nanowire-based batteries could be commercially viable, and potentially the next big break in battery technology.

When the loaves in your breadbox begin to develop a moldy exterior caused by fungi, they tend to find a new home at the bottom of a trash can. However, researchers have recently developed some pretty interesting results that suggest bread mold could be the key to producing more sustainable electrochemical materials for use in rechargeable batteries.

For the first time, researchers were able to show that the fungus Neurospora crassa (better known as the enemy to bread) can transform manganese into mineral composites with promising electrochemical properties.

(MORE: Read the full paper.)

“We have made electrochemically active materials using a fungal manganese biomineralization process,” says Geoffrey Gadd of the University of Dundee in Scotland. “The electrochemical properties of the carbonized fungal biomass-mineral composite were tested in a supercapacitor and a lithium-ion battery, and it [the composite] was found to have excellent electrochemical properties. This system therefore suggests a novel biotechnological method for the preparation of sustainable electrochemical materials.”

This from University of Dundee:

In the new study, Gadd and his colleagues incubated N. crassa in media amended with urea and manganese chloride (MnCl2) and watched what happened. The researchers found that the long branching fungal filaments (or hyphae) became biomineralized and/or enveloped by minerals in various formations. After heat treatment, they were left with a mixture of carbonized biomass and manganese oxides. Further study of those structures show that they have ideal electrochemical properties for use in supercapacitors or lithium-ion batteries.

Read the full article here.

The manganese oxides in the lithium-ion batteries are showing an excellent cycling stability and more than 90 percent capacity after 200 cycles.

An interdisciplinary team, including 32 year ECS member Stuart Licht and ECS student member Matthew Lefler, has developed a way to make electric vehicles that are not only carbon neutral, but carbon negative – capable of reducing the amount of atmospheric carbon dioxide as they operate by transforming the greenhouse gas.

By replacing the graphite electrodes that are currently being used in the development of lithium-ion batteries for electric cars with carbon materials recovered from the atmosphere, the researchers have been able to develop a recipe for converting collected carbon dioxide into batteries.

This from Vanderbilt University:

The team adapted a solar-powered process that converts carbon dioxide into carbon so that it produces carbon nanotubes and demonstrated that the nanotubes can be incorporated into both lithium-ion batteries like those used in electric vehicles and electronic devices and low-cost sodium-ion batteries under development for large-scale applications, such as the electric grid.

Read the full article.

The research is not the first time scientists have shown progress in collecting and converting harmful greenhouse gases from the environment.

Typically, carbon dioxide conversion revolves around transforming the gas into low-value fuels such as methanol. These conversions often do not justify the costs.

(MORE: Read “Carbon Nanotubes Produced from Ambient Carbon Dioxide for Environmentally Sustainable Lithium-Ion and Sodium-Ion Battery Anodes.“)

However, the new process produces better batteries that are not only expected to be efficient, but also cost effective.

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With the transportation sectors of industrialized countries on the rise and greenhouse gas emissions at an all-time high, many scientists and engineers are searching for the next-generation of transportation. From hybrid to electric to hydrogen, alternative energy sources for vehicles are being explored and tested throughout the scientific community. Now, many are wondering which technology will win in the race between battery- and hydrogen-powered cars.

A recent open access paper published in the Journal of The Electrochemical Society (JES) explores this topic. Authors Hubert A. Gasteiger, Jens-Peter Suchsland, and Oliver Gröger have outlined the technological barriers for next-generation vehicles in “Review—Electromobility: Batteries or Fuel Cells?” This paper comes as part of the recent JES Collection of Invited Battery Review Papers.

The majority of today’s vehicles depend on petroleum-based products in internal combustion engines to operate. The burning of these fuels results in the emission of greenhouse gasses. The majority of these transportation sector greenhouse gas emissions do not come from large modes of transportation such as aircrafts or ships—but are primarily produced by cars, trucks, and SUVs.

In the recently published review, the authors describe the possibilities of extended range electric vehicles, the challenges in hydrogen fuel cell vehicles, and the potential for new materials to be used in these applications.

Read this open access paper and read the rest of the JES Collection of Invited Battery Review Papers.

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The Korea Section Symposium (Organizers: Prof. Yung-Eun Sung, Prof. Soo-Kil Kim and Dr. Byoung Koun Min) was held on April 2, 2015 at the Kimdaejung Convention Center in Gwangju, Korea.

This year, the event was held as a Joint Symposium with the Korea Institute of Science and Technology, with the title “ECS Korea Section-KIST Joint Symposium on Electrochemical CO₂ Conversion.” It was composed of seven talks on electrocatalysts and systems for electrochemical reduction of CO₂.

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Flow Batteries for Grid-Scale Energy Storage
Large-scale energy storage is required to meet a multitude of current energy challenges. These challenges include modernizing the grid, incorporating intermittent renewable energy sources (so as to dispatch continuous electrical energy), improving the efficiency of electricity transmission and distribution, and providing flexibility of storage independent of geographical and geological location. Read more.

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ECS publications span the entire subject area of electrochemistry and solid-state science. The Society publishes peer-reviewed technical journals, proceedings, monographs, conference abstracts, and a quarterly news magazine. The Society’s oldest title, Journal of The Electrochemical Society, has been in continuous publication since the Society’s founding in 1902.

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