Two-dimensional layered structure of graphene and its silicon carbide-free integration with silicon can serve as a prototype in advancing silicon anodes to commercially viable technology.
Source: Nature Communications

Researchers from various institutes across Korea have found a way to nearly double the life of the lithium-ion battery.

In an ever-pressing race to create a more efficient and longer-lasting battery for electronics, researchers across the globe are looking toward alternative materials to make the li-ion battery stronger. A team of researchers associated with Samsung’s Advanced Institute of Technology, including ECS member Jang Wook Choi, have combined silicon and graphene to yield an amazing increase in lithium-ion battery efficiency.

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The new structure has high mobility of Na+ ions and a robust framework.
Image: Nature Communications

With the demand for hand-held electronics at an all-time high, the costs of the materials used to make them are also rising. That includes materials used to make lithium batteries, which is a cause for concern when projecting the development of large-scale grid storage.

In order to find an alternative solution to the high material costs connected with lithium batteries, the researchers at the Australian Nuclear Science and Technology Organisation (ANSTO) and the Institute of Physics at the Chinese Academy of Science in Beijing have begun focusing their attention on sodium-ion batteries.

The science around sodium-ion batteries dates back to the 1980s, but the technology never took off due to resulting low energy densities and short life cycles.

However, the new research looks to combat those issues by improving the properties of a class of electrode materials by manipulating their electron structure in the sodium-ion battery.

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PNNL scientist Jian Zhi Hu shows a tiny experimental battery mounted in NMR apparatus.
Image: PNNL

While working on a unique lithium-germanide battery, Pacific Northwest National Laboratory (PNNL) researchers knew something was happening inside the battery to dramatically increase its energy storage capacity, but they couldn’t see it. With no way to analyze the reaction occurring, the researchers could not understand the process. In order to solve the problem, the researchers developed a novel nuclear magnetic resonance (NMR) technique to allow insight and understanding of the electrochemical reactions taking place in the battery. Essentially, they have developed an NMR “camera.”

In the end, this leaves the scientists with not only a novel lithium-germanide battery with a distinctly high energy density, but also an NMR device that can be used to examine reactions as they happen inside the battery.

This from PNNL:

By using the NMR process to look inside the battery and observe this reaction as it happened, the scientists found a way to protect the germanium from expanding and becoming ineffective after it takes on lithium. The secret proved to be forming the germanium into tiny “wires” and encasing them in small, protective carbon tubes to limit the expansion. This technique significantly stabilizes battery performance. Without embedding germanium in carbon tubes, a battery performs well for a few charging-discharging cycles, but fades rapidly after that. Using the “core-shell” structure, however, the battery can be discharged and charged thousands of times.

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Recently, scientists have been looking at the Japanese paper-folding art of origami as inspiration for novel flexible energy-storage technologies. While there have been breakthroughs in battery flexibility, there has yet to be a successful development of stretchable batteries. Now, researchers from Arizona State University have unveiled a way to make batteries stretch, yielding big potential outcomes for wearable electronics.

The Arizona State University research team includes ECS member and advisor of the ECS Valley of the Sun student chapter, Candace K. Chan. Chan and the rest of the team were inspired by a variation of origami called kirigami when developing this new generation of lithium-ion batteries.

According to the researchers, the new battery can be stretched more than 150 percent of its original size and still maintain full functionality.

ECS treasurer E.J. Taylor (Founder & CTO of Faraday Technology), recently forwarded us a story from The Economist featuring ECS members and their contributions to research and development on the ever-improving lithium-ion battery.

Since the battery’s commercialization by Sony in the early 1990s, the lithium-ion battery has improved to produce better laptops, smartphones, and even power electric cars.

Vincent Battaglia, ECS member and head of the Electrochemical Technologies Group at Lawrence Berkeley National Laboratory, states that the lithium-ion battery “is almost an ideal battery.” With its light weight and recharging capabilities, the battery has received much attention from researchers globally.

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The “designer carbon” improved the supercapacitor’s electrical conductivity threefold compared to electrodes made of conventional activated carbon.
Image: Stanford University

Stanford University researchers have developed a new “designer carbon” that can be fine-tuned for a variety of applications, including energy storage and water filters.

The newly developed carbon material has shown that it can significantly improve the power delivery rate of supercapacitors and boost the performance of energy storage technologies.

“We have developed a ‘designer carbon’ that is both versatile and controllable,” said Zhenan Bao, past member of ECS and the senior author of the study. “Our study shows that this material has exceptional energy-storage capacity, enabling unprecedented performance in lithium-sulfur batteries and supercapacitors.”

(PS: Check out some of Bao’s past papers in the Digital Library!)

Not only is the new carbon an improvement over existing versions, it also has a huge potential scope and is inexpensive to produce.

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ECS’s job board keeps you up-to-date with the latest career opportunities in electrochemical and solid state science. Check out the latest openings that have been added to the board.

P.S. Employers can post open positions for free!

Senior Manager, External Technology
Energizer – Westlake, Ohio
Candidate is required to establish agreements and negotiate contracts with technology leaders including companies (public, private and start-up) and universities and national laboratories. Contracts will be vetted internally with line management and legal prior to executing.

Electrochemistry Senior Engineer
Johnson Controls – Milwaukee, WI
The electrochemists uses his/her knowledge and understanding of the chemical and/or electrochemical processes that occur during the conversion of materials in the active masses of a battery, and how these phenomena affect battery performance under different applications, to recommend design or component changes to target performance specifications.

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The high-performance 3D microbattery is suitable for large-scale on-chip integration.
Image: Engineering at Illinois

Engineers from the University of Illinois at Urbana-Champaign’s College of Engineering have developed a high-performance 3D microbattery applicable for large-scale on-chip integration with microelectronic devices.

“This 3D microbattery has exceptional performance and scalability, and we think it will be of importance for many applications,” said Paul Braun, professor of materials science and engineering at Illinois.

“Micro-scale devices typically utilize power supplied off-chip because of difficulties in miniaturizing energy storage technologies. A miniaturized high-energy and high-power on-chip battery would be highly desirable for applications including autonomous microscale actuators, distributed wireless sensors and transmitters, monitors, and portable and implantable medical devices.”

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We recently sat down with the University of Iowa’s Johna Leddy, an established researcher in electrochemical power sources and a highly respected mentor to the students of the Leddy Lab. Listen as we talk about the energy infrastructure, Dr. Leddy’s career in academia, how to make the world a better place, and more!

Listen below and download this episode and others for free through the iTunes Store, SoundCloud, or our RSS Feed.

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Engineers developed this one-material battery by sprinkling carbon (red) into each side of a new material (blue) that forms the electrolyte and both electrodes at the ends of the battery.
Source: Maryland NanoCenter

ECS student member Fudong Han and former member Chunsheng Wang have developed a novel solid state battery comprised of just one material that can both move and store electricity.

This new battery could prove to be revolutionary in the area of solid state batteries due to its incorporation of electrodes and electrolytes into a single material.

“Our battery is 600 microns thick, about the size of a dime, whereas conventional solid state batteries are thin films — forty times thinner. This means that more energy can be stored in our battery,” said Han, the first author of the paper and a graduate student in Wang’s group.

This from the University of Maryland:

The new material consists of a mix of sulfur, germanium, phosphorus and lithium. This compound is used as the ion-moving electrolyte. At each end, the scientists added carbon to this electrolyte to form electrodes that push the ions back and forth through the electrolyte as the battery charges and discharges. Like a little bit more sugar added at each end of a cookie-cream mixture, the carbon merely helps draw the electricity from side to side through the material.

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