Image: MIT

New lithium-oxygen battery technology proposed by researchers from MIT, Argonne National Laboratory, and Peaking University, promises a scalable, cheap, and safe option in energy storage.

There is immense promise for lithium-oxygen batteries in such applications as electric cars and portable electronics. In fact, they are between five and 15 times more efficient than lithium-ion batteries in transportation applications due to their high energy output potential in proportion to their weight.

But there have been complications in developing and especially implementing these batteries in the marketplace. Primarily, they’ve been known to waste energy and degrade quickly.

But this new study, co-authored by ECS member and past IMLB chair Khalil Amine, states that the theoretical potential for lithium-oxygen batteries could be met while overcoming some of the biggest barriers prohibiting the technology.

Once of the primary focuses of the group was overcoming the mismatch in voltages that happens in charging and discharging the battery. Because the output voltage is more than 1.2 volts lower that that used to charge, there is typically a significant power loss.

“You waste 30 percent of the electrical energy as heat in charging,” says Ju Li, professor at MIT and co-author of the paper. “It can actually burn if you charge it too fast.”

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Image: Toyohashi University

As the landscape of energy harvesting evolves, so do the devices that store that energy. According to researchers from Toyohashi University, all-solid-state lithium rechargeable batteries are at the top of the list of promising future energy storage technologies due to their high energy density, safety, and extreme cycle stability.

ECS member Yoji Sakurai and a team from the university’s Department of Electrical and Electronic Information Engineering recently published a paper detailing their development to advance the all-solid-state batteries, which pushes past barriers related to electrochemical performance.

(MORE: Read Sakurai’s previously published paper in ECS Electrochemistry Letters.)

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Image: Toshiyuki Imai/Flickr

A new report by TechXplore examines a recently published review paper on the potential in nanomaterials for rechargeable lithium batteries. In the paper, lead-author and ECS member Yi Cui of Stanford University, explores the barriers that still exist in lithium rechargeables and how nanomaterials may be able to lend themselves to the development of high-capacity batteries.

When trying to design affordable batteries with high-energy densities, researchers have encountered many issues, including electrode degradation and solid-electrolyte interphase. According to the paper’s authors, possible solutions for many of these hurdles lie in nanomaterials.

Cui’s comprehensive overview of rechargeable lithium batteries and the potential of nanaomaterials in these applications came from 100 highly-reputable publications, including the following ECS published papers:

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Cathode particles treated with the carbon dioxide-based mixture show oxygen vacancies on the surface.
Image: Laboratory for Energy Storage and Conversion, UC San Diego

An international team of researchers has recently demonstrated a 30 to 40 percent increase in the energy storage capabilities of cathode materials.

The team, led by ECS member and 2016 Charles W. Tobias Young Investigator Award winner, Shirley Meng, has successfully treated lithium-rich cathode particles with a carbon dioxide-based gas mixture. This process introduced oxygen vacancies on the surface of the material, allowing for a huge boost to the amount of energy stored per unit mass and proving that oxygen plays a significant role in battery performance.

This greater understanding and improvement in the science behind the battery materials could accelerate developments in battery performance, specifically in applications such as electric vehicles.

(READ: “Gas-solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries“)

“We’ve uncovered a new mechanism at play in this class of lithium-rich cathode materials,” says Meng, past guest editor of JES Focus Issue on Intercalation Compounds for Rechargeable Batteries. “With this study, we want to open a new pathway to explore more battery materials in which we can control oxygen activity.”

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CC0 Public Domain

When lithium-ion pioneers M. Stanley Whittingham, Adam Heller, Michael Thackeray, and of course, John Goodenough were in the initial stages of the technology’s development in the 1970s through the late 1980s, there was no clear idea of just how monumental the lithium-based battery would come to be. Even up to a few years ago, the idea of an electric vehicle or renewable grid dependent on lithium-ion technology seemed like a pipe dream. But now, electric vehicles are making their way to the mainstream and with them comes the commercially-driven race to acquire lithium.

Just look at the rise of Tesla and success of the Nissan LEAF. Not only are these cars speaking to a real concern for environmental protection, they’re also becoming the more affordable option in transportation. For example, the LEAF goes for less than $25,000 and gets more than 80 miles per charge. Plus, electric vehicles can currently run on electricity that’s costing around $0.11 per kWh, which is roughly equivalent to $0.99 per gallon. The last year alone saw a 60 percent spike in the sale of electric vehicles.

“Electric cars are just plain better,” says James Fenton, director of the Florida Solar Energy Center and newly appointed ECS Secretary. “They’re cheaper to buy up front and they’re cheaper to operate, which years ago, was not the case.”

All things considered, lithium may just be the number one commodity of our time.

But this movement is not specific to the U.S. alone. In Germany – a country dedicated to a renewable future – there is a mandate that all new cars in the country will have to be emission-free by 2030. Similarly in Norway, the government is looking to ban gasoline-powered cars by 2025.

So with the transportation sector heading away from gasoline-powered cars and toward lithium battery-based vehicles globally, what will that do to lithium supplies?

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Elon Musk via Insider Monkey/Flickr

By now you’ve probably heard of the big merger between automotive innovator Tesla and rooftop solar guru SolarCity. Elon Musk, CEO of Tesla, claims that the integration will create “the world’s first vertically integrated energy company,” set to offer the full spectrum of clean energy products to customers.

While both companies have gotten a lot of attention from investors over the years, there has been a lot of skepticism when it comes to the financial future of the joining of these two companies.

First, neither companies have made any money independently last year. In fact, combined they lost $1.7 billion.

But the financial losses are not the real concern. As MIT Technology Review points out, the technology that would make an end-to-end clean energy system feasible has not yet been developed by either company.

Musk’s vision for the newly integrated company is to set up consumers to solely utilize renewable energy. That would mean electric vehicles, rooftop solar panels, and of course, a battery to store energy when the sun goes down.

Although Tesla has already premiered their home Powerwall battery, it fell short of expectations. The seven-kilowatt-hour battery was expected to be able to store enough energy to power your home and send energy back to the grid (converting homes to microgrids) for a flat rate of $3,000, but the actual cost turned out to be closer to $10,000.

Pair that cost with SolarCity panels and analyses show that you’ll be paying over double for your electricity than a typical rate user.

“At the end of the day, the Powerwall has the same Li-ion battery cells in it as any other Li-ion-based storage product: Asian-sourced batteries that are arranged in packs,” Jay Whitacre, ECS member and professor at Carnegie Mellon University, told MIT Technology Review. “It’s basically off-the-shelf cell technology.”

Debate Panel members – left to right: Professor Clare Grey (University of Cambridge), Dr Yann Laot (TOTAL, France), MEP Julie Girling (Chair), Dr Rosa Palacin, (ICMAB-CSIC, Spain), Professor Patrik Johnansson, (Chalmers University of Technology, Sweden), Dr Anne de Guibert (SAFT, France)

The first 2016, biannual meeting of the ALISTORE European Research Institute of leading European battery technology scientists took place in the CSIC (Consejo Superior de Investigaciones Cientificas) (National Research Council of Spain) European Office in Brussels across the 14th and 15th June 2016.

The two day event started with the theme “Future aspects of Materials Sciences & Electrochemistry research in the European Green Energy Economy: The role of the ALISTORE European Research Institute.” Discussion topics included : the current basic economics of energy storage technologies and those which can be coupled to renewable energy systems, the current bottlenecks in the improved performance greener battery supply chain and how we can create even better European – as opposed to national – efforts of R&D on energy storage solutions leading to faster product development and entry into the marketplace.

Member of the Environment Committee in the European Parliament Julie Girling chaired the debate by the scientific leaders in the first part of the meeting. The panel of scientific experts who led the debate included Dr. Anne de Guibert (SAFT, France, Industrial Club Member), Prof. Clare Grey (University of Cambridge, UK, Academic Member), Prof. Patrik Johansson (Chalmers University of Technology, Sweden, Academic Member), Dr .Yann Laot (TOTAL, France, Industrial Club Member), Dr. M. Rosa Palacin (ICMAB-CSIC, Spain, Academic Member).

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Image: Heinz Traimer/Wikimedia Commons

We may understand melanin best as the pigment that dictates our skin tone, but these pigments are actually super plentiful – existing in almost every organism on earth. While melanin is all around us, there is still much to learn about its chemical structure.

A group of researchers from Carnegie Mellon University set out to better understand melanin, and in doing so, found that its chemical structure may be conducive to creating certain kinds of batteries.

“Functionally, different types of melanin molecules have quite different chemistries, so putting them together is a little like solving a jigsaw puzzle, with each molecule a puzzle piece,” says Venkat Viswanathan, ECS member and co-author of the study. “You could take any number of these pieces and mix and match them, even stack them on top of each other. So what we researched was, which of these arrangements is really correct?”

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In late 2015, a team of Cambridge University researchers led by ECS member Clare Grey, detailed research in the journal Science on the path to the “ultimate” battery. According to the study, the researchers stated they had successfully demonstrated how to overcome many of the problems preventing the theoretically promising lithium-air battery from being commercially viable.

The key component to this research relies on a highly porous, “fluffy” carbon electrode made from graphene. The researchers cautioned that although the preliminary results were very promising, much work was yet to be done to take lithium-air batteries from the lab to the marketplace.

However, the research got many scientists in energy science and technology talking. Like all groundbreaking results, there has been much discussion and some controversy over the research published by Grey and her team.

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Image: Rob Nunn/Flickr

Researchers from the University of Maryland and the U.S. Army Research Laboratory have developed a lithium-ion battery that is safer, cheaper, more powerful, and extremely environmentally friendly – all by adding a pinch of salt.

The team, led by ECS members Chunsheng Wang and Kang Xu, built on previous “water-in-salt” lithium-ion battery research – concluding that by adding a second salt to the water-based batteries, efficiency levels rise while safety risks and environmental hazards decrease.

(WATCH: Wang’s presentation at the fifth international ECS Electrochemical Energy Summit, entitled “A Single Material Battery.”)

“Our invention has the potential to transform the energy industry by replacing flammable, toxic lithium ion batteries with our safe, green water-in-salt battery,” says Wang, professor in the University of Maryland’s Department of Chemical & Biomolecular Engineering. “This technology may increase the acceptance and improve the utility of battery-powered electric vehicles, and enable large-scale energy storage of intermittent energy generators like solar and wind.”

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