The Electrochemical Society hosted Prof. Jill Venton’s live webinar, “Novel Carbon Electrodes for Neurochemistry,” on May 26, 2021. Below are answers to questions posed after the presentation.

NOTE: Registration is required to view the webinar.

Dr. B. Jill Venton is Professor and Chair of the Department of Chemistry at the University of Virginia (UVA), U.S. She is also affiliated with the Neuroscience Graduate Program and UVA Brain Institute. Dr. Venton received her BS in Chemistry from the University of Delaware, U.S.; her PhD in Chemistry from The University of North Carolina at Chapel Hill, U.S.; and did postdoctoral research at the University of Michigan, U.S. Her career at UVA started in 2005 and she became Chair of the Department of Chemistry in 2019. The Venton Group’s research focuses on developing analytical chemistry tools for neuroscience research. The lab studies many neuroscience diseases, from Parkinson’s, to addiction, stroke, and aging.

Q&A

Is it a normal practice to have widely different concentrations of analyte while comparing their CVs? (more…)

Dr. Rodney Ruoff delivers the ECS Lecture on May 31

The ECS Lecture at the Plenary Session of the 239th ECS Meeting with IMCS18 will be delivered by Dr. Rodney Ruoff, Distinguished Professor in the Departments of Chemistry and Materials Science, and the School of Energy Science and Chemical Engineering at the Ulsan National Institute of Science and Technology (UNIST), South Korea, and Director of the Center for Multidimensional Carbon Materials (CMCM). The Plenary Session is from 2100-2200h EST on Monday, May 31, after which the content will be available through June 26, 2021. The 239th ECS Meeting with IMCS18 takes place in a digital format. There is no cost to participate, however pre-registration is required. (more…)

On June 24, 2020, Dr. Paul Kenis, 2020 winner of the Energy Technology Division Research Award, presented his talk on “Electrochemical CO₂ Reduction: Path Towards a Carbon Neutral Chemical Industry?” via a live webinar presentation.

Dr. Kenis’s talk covered a summary of the status of CO₂ electrocatalysis, the techno-economic and life-cycle analysis of CO₂ electrolysis to identify remaining hurdles, and the prospects of CO₂ electrolysis technology contributing to a future sustainable chemical industry.

View Dr. Kenis’s webinar presentation, here.

Following the talk, attendees were given the opportunity to ask Dr. Kenis questions in a Q&A session, available below. (more…)

New research sheds light on the effectiveness and value of carbon-pricing incentive programs.

In a new paper, based on analysis of a 2015 pilot program on the Yale University campus, researchers examine internal carbon-pricing strategies, including different models of implementation.

Further, they illustrate how the Yale project, which has since expanded into a campus-wide initiative, has provided empirical evidence of the effectiveness of these price signals.

More than 600 major companies—from BP to Microsoft—have adopted carbon-pricing programs to spur energy conservation and control their carbon emissions. But researchers have previously not analyzed or publicly reported the effectiveness of these efforts.

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Scientists have turned wood into an electrical conductor by making its surface graphene.

Chemist James Tour of Rice University and his colleagues used a laser to blacken a thin film pattern onto a block of pine. The pattern is laser-induced graphene (LIG), a form of the atom-thin carbon material discovered at Rice in 2014.

“It’s a union of the archaic with the newest nanomaterial into a single composite structure,” Tour says.

Previous iterations of LIG were made by heating the surface of a sheet of polyimide, an inexpensive plastic, with a laser. Rather than a flat sheet of hexagonal carbon atoms, LIG is a foam of graphene sheets with one edge attached to the underlying surface and chemically active edges exposed to the air.

Not just any polyimide would produce LIG, and some woods work better than others, Tour says. The research team tried birch and oak, but found that pine’s cross-linked lignocellulose structure made it better for the production of high-quality graphene than woods with a lower lignin content. Lignin is the complex organic polymer that forms rigid cell walls in wood.

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Scientists have found that a common enzyme can speed up—by 500 times—the rate-limiting part of the chemical reaction that helps the Earth lock away, or sequester, carbon dioxide in the ocean.

“While the new paper is about a basic chemical mechanism, the implication is that we might better mimic the natural process that stores carbon dioxide in the ocean,” says lead author Adam Subhas, a California Institute of Technology (Caltech) graduate student.

Simple problem, complex answer

The researchers used isotopic labeling and two methods for measuring isotope ratios in solutions and solids to study calcite—a form of calcium carbonate—dissolving in seawater and measure how fast it occurs at a molecular level.

It all started with a very simple, very basic problem: measuring how long it takes for calcite to dissolve in seawater.

“Although a seemingly straightforward problem, the kinetics of the reaction is poorly understood,” says Berelson, professor of earth sciences at the University of Southern California Dornsife College of Letters, Arts, and Sciences.

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By: Elton Santos, Queen’s University Belfast

Scientists have found a way to make carbon both very hard and very stretchy by heating it under high pressure. This “compressed glassy carbon”, developed by researchers in China and the US, is also lightweight and could potentially be made in very large quantities. This means it might be a good fit for several sorts of applications, from bulletproof vests to new kinds of electronic devices.

Carbon is a special element because of the way its atoms can form different types of bonds with each other and so form different structures. For example, carbon atoms joined entirely by “sp³” bonds produce diamond, and those joined entirely by “sp²” bonds produce graphite, which can also be separated into single layers of atoms known as graphene. Another form of carbon, known as glassy carbon, is also made from sp² and has properties of both graphite and ceramics.

But the new compressed glassy carbon has a mix of sp³ and sp² bonds, which is what gives it its unusual properties. To make atomic bonds you need some additional energy. When the researchers squeezed several sheets of graphene together at high temperatures, they found certain carbon atoms were exactly in the right position to form sp³ bonds between the layers.

By studying the new material in detail, they found that just over one in five of all its bonds were sp³. This means that most of the atoms are still arranged in a graphene-like structure, but the new bonds make it look more like a large, interconnected network and give it greater strength. Over the small scale of individual graphene sheets, the atoms are arranged in an orderly, hexagonal pattern. But on a larger scale, the sheets are arranged in a disorderly fashion. This is probably what gives it the combined properties of hardness and flexibility.

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The “queen of carbon science,” Mildred Dresselhaus, has passed away at the age of 86.

Dresselhaus was a recipient of both the Presidential Medal of Freedom and National Medal of Science, solidifying her role as a leader in the scientific community and an advocate for women in STEM.

Among her scientific contributions, Dresselhaus is perhaps most known for playing a key role in unlocking the mysteries of carbon. Her contributions to fundamental research in the electronic structure of semi-materials and initial insight into fullerenes have made an extensive impact on the scientific community.

“We lost a giant — an exceptionally creative scientist and engineer who was also a delightful human being,” MIT President L. Rafael Reif wrote in a statement. “Among her many ‘firsts,’ in 1968, Millie became the first woman at MIT to attain the rank of full, tenured professor. She was the first solo recipient of a Kavli Prize and the first woman to win the National Medal of Science in Engineering.”

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