A new study describes the mechanics behind an early key step in artificially activating carbon dioxide so that it can rearrange itself to become the liquid fuel ethanol.

Solving this chemical puzzle may one day lead to cleaner air and renewable fuel.

The scientists’ ultimate goal is to convert harmful carbon dioxide (CO2) in the atmosphere into beneficial liquid fuel. Currently, it is possible to make fuels out of CO2—plants do it all the time—but researchers are still trying to crack the problem of artificially producing the fuels at large enough scales to be useful.

Theorists at Caltech used quantum mechanics to predict what was happening at atomic scales, while experimentalists at the Department of Energy’s (DOE) Lawrence Berkeley National Lab (Berkeley Lab) used X-ray studies to analyze the steps of the chemical reaction.

“One of our tasks is to determine the exact sequence of steps for breaking apart water and CO2 into atoms and piecing them back together to form ethanol and oxygen,” says William Goddard professor of chemistry, materials science, and applied physics, who led the Caltech team. “With these new studies, we have better ideas about how to do that.”

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In an effort to increase security on airplanes, the U.S. government is considering expanding a ban on lithium-ion based devices from cabins of commercial flights, opting instead for passengers to transport laptops and other electronic devices in their checked luggage in the cargo department. However, statistics from the Federal Aviation Administration suggest that storing those devices in the cargo area could increase the risk of fires.

The FAA reports that batteries were responsible for nine airline fires in 2014. The number grew to 16 in 2015 and further to 31 in 2016. Most fires were able to be extinguished by passengers.
According to Homeland Security Secretary John Kelly, the U.S. government is considering expanding the ban to 71 additional airports.

(READ: “What’s Next for Batteries?” with Robert Kostecki.)

Mainstream concern regarding lithium-ion battery safety became widespread in 2016 when videos of hoverboards exploding began to emerge. Since then, news reports of smartphone and laptop batteries have emerged.

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In its first “Science for Solving Society’s Problems Challenge,” ECS partnered with the Bill & Melinda Gates Foundation to leverage the brainpower of the many scientists in electrochemistry and solid state science and technology that regularly attend ECS meetings. From this project, seven presentations were selected, with a total of $360,000 awarded to pursue research projects addressing world sanitation problems.

The powerPAD, a collaboration among Neus Sabaté, Juan Pablo Esquivel, and Erik Kjeang, was one of the projects selected to receive $50,000 in funding. Now, just over two years later, the researchers are discussing their findings and how their work has transformed over time.

“As originally proposed, the developed battery is completely made of organic materials such as cellulose, carbon electrodes, beeswax and organic redox species, and can be fabricated by affordable methods with low energy consumption,” Esquivel told ECS in an email. “After it’s used, the battery can be disposed of in an organic waste container or even discarded in the field, because it biodegrades by the action of microorganisms present in soils and water bodies. In the article we have shown that this biodegradable battery can substitute for a Li-ion coin cell battery to run a portable water monitoring device. The battery is activated upon the addition of a drop of the same water sample that is analyzed.”

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In 2016, Solar Impulse 2 was the first solar-powered electrified aircraft to make a trip around the world. But that aircraft wasn’t the first to partake in electric flight, nor will it be the last.

Since the development of the battery-powered Militky MB-E1 in the early 1970s, there has been excitement surrounding the promise of an electric aircraft. However, many of the concepts being floated around by aerospace companies assume huge improvements in current battery technology.

The problem? According to a recently published article in Wired, current battery technology does not offer the power-to-weight ratio needed to make battery-powered planes feasible.

But battery technology has taken leaps over the past few years. Energy storage devices are become more efficient and lighter simultaneously. But how long will it take to be able to pack enough energy into a device while remaining light enough to glide through the sky?

“There’s already been a lot of progress,” Venkat Srinivasan, battery expert with Argonne National Lab, told Wired. “It’s not the same ballpark as Moore’s law progress because it’s chemistry, not electronics, but it’s still very good.”

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The development of the lithium-ion battery has helped enable the modern day electronics revolution, making possible everything from cellphones to laptops to electric vehicles and even grid-scale energy storage.

However, those batteries have limited lifespans. Battery expert Daniel P. Abraham is looking to address that.

“As your cellphone battery ages, you notice that you have to plug it in more often,” says Abraham, ECS member and scientist at Argonne National Laboratory. “Over a period of time, you are not able to store as much charge in the battery, and that is the process we call capacity fade.”

Abraham is a co-author of an open access paper recently published in the Journal of The Electrochemical Society, “Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells,” which addresses the question of why your battery doesn’t age well.

A majority of today’s electronic devices are powered by the lithium-ion battery. In order for the battery to store and release energy, lithium ions move back and forth between the positive and negative electrodes through an electrolyte.  In theory, the ions could travel back and forth an infinite number of times, resulting in a battery that lasts forever.

But that’s not what happens in the batteries that power your laptops and your electric vehicles. According to Abraham, unwanted side reactions often occur as ions move between the electrodes, resulting in batteries that lose capacity over time.

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The electric vehicle market continues to build momentum every year, with consumers around the world growing more interested. But in order for EVs to pave the way for the future of transportation, more efficient, longer-lasting batteries will need to be developed.

That’s where ECS member Jeff Dahn, leader of Tesla’s researcher partnership through his Dalhousie University research group, comes in. Recently, Dahn and his team unveiled new chemistry that could increase battery lifecycle at high voltages without significant degradation.

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The consumer demand for seamless, integrated technology is on the rise, and with it grows the Internet of Things, which is expected to grow to a multitrillion-dollar market by 2020. But in order to develop a fully integrated electronic network, flexible, lightweight, rechargeable power sources will be required.

A team of researchers from Ulsan National Institute of Science and Technology is looking to address that issue, developing inkjet-printed batteries that can be modified to fit devices of any shape and size. The team reports that the newly developed inks can be printed onto paper to create a new class of printed supercapacitors.

(READ: Rise of Cyber Attacks: Security in the Digital Age)

This from Ulsan National Institute of Science and Technology:

The process involves using a conventional inkjet printer to print a preparatory coating—a ‘wood cellulose-based nanomat’—onto a normal piece of A4 paper. Next, an ink of activated carbon and single-walled nanotubes is printed onto the nanomat, followed by an ink made of silver nanowires in water. These two inks form the electrodes. Finally, an electrolyte ink—formed of an ionic liquid mixed with a polymer that changes its properties when exposed to ultraviolet light—is printed on top of the electrodes. The inks are exposed at various stages to ultraviolet irradiation and finally the whole assembly is sealed onto the piece of paper with an adhesive film.

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Like all things, batteries have a finite lifespan. As batteries get older and efficiency decreases, they enter what researchers call “capacity fade,” which occurs when the amount of charge your battery could once hold begins to decrease with repeated use.

But what if researchers could reduce this capacity fade?

That’s what researchers from Argonne National Laboratory are aiming to do, as demonstrated in their open access paper, “Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells,” which was recently published in the Journal of The Electrochemical Society.

The capacity of a lithium-ion battery directly correlates to the amount of lithium ions that can be shuttled back and forth as the device is charged and discharged. Transition metal ions make this shuttling possible, but as the battery is cycled, some of those ions get stripped out of the cathode material and end up at the battery’s anode.

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Researchers from Columbia University School of Engineering and Applied Science recently developed a method that could result in safer, longer-lasting, bendable lithium-ion batteries. To do this, the team applied ice-templating to control the structure of the solid electrolyte for lithium-ion batteries.

Recent reports of cell phones and hoverboards bursting into flames have made people aware of the safety concerns related to the lithium-ion battery’s liquid electrolyte. The researchers behind this new work decided to confront the safety issues by exploring the use of a solid electrolyte, therefore developing an all-solid-state lithium battery.

[The researchers] were interested in using ice-templating to fabricate vertically aligned structures of ceramic solid electrolytes, which provide fast lithium ion pathways and are highly conductive. They cooled the aqueous solution with ceramic particles from the bottom and then let ice grow and push away and concentrate the ceramic particles. They then applied a vacuum to transition the solid ice to a gas, leaving a vertically aligned structure. Finally, they combined this ceramic structure with polymer to provide mechanical support and flexibility to the electrolyte.

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A new mathematical model may help researchers design new materials for use in high-power batteries. According to the research team, the model could benefit chemists and materials scientists who typically rely on a trial and error method when developing new materials for batteries and capacitors.

“The potential here is that you could build batteries that last much longer and make them much smaller,” says Daniel Tartakovsky, co-author of the study. “If you could engineer a material with a far superior storage capacity than what we have today, then you could dramatically improve the performance of batteries.”

Demand for affordable, efficient energy storage continues to increase as more entities transition toward renewable energy. While there are many researchers working in the area of energy storage, the team behind this development is looking at the field in a new light.

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