Carbon dioxideA team of researchers from the University of Toronto is looking to give wasted materials new value by developing a new catalyst that could help recycle carbon dioxide into plastic.

According to a new study, the researchers have successfully used a new technique to efficiently convert carbon dioxide to ethylene, which can then be processed to make polyethylene, the most common plastic used in making packaging, bottles, and toys.

By using a copper catalyst, the team was able to achieve the desired result of ethylene production. However, controlling the catalyst was one of the technological challenges the team had to overcome.

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Carbon dioxideNew research sheds light on the effectiveness and value of carbon-pricing incentive programs.

In a new paper, based on analysis of a 2015 pilot program on the Yale University campus, researchers examine internal carbon-pricing strategies, including different models of implementation.

Further, they illustrate how the Yale project, which has since expanded into a campus-wide initiative, has provided empirical evidence of the effectiveness of these price signals.

More than 600 major companies—from BP to Microsoft—have adopted carbon-pricing programs to spur energy conservation and control their carbon emissions. But researchers have previously not analyzed or publicly reported the effectiveness of these efforts.

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Carbon dioxideWhile pursing work on the highly desirable but technically challenging lithium-air battery, researchers unexpectedly discovered a new way to capture and store carbon dioxide. Upon creating a design for a lithium-CO2 battery, the research team found a way to isolate solid carbon dust from gaseous carbon dioxide, all while being able to separate oxygen.

As global industry, technology, and transportation grows, the consumption of fossil fuels has increased. According to the U.S. Environmental Protection Agency, the burning of petroleum-based products has resulted in 6,587 million of metric tons of carbon dioxide released into the environment in 2015. The emission of greenhouse gasses like carbon dioxide trap heat in the atmosphere, which researches have linked the global warming. Because of this, capturing and converting carbon emissions has become a highly researched area.

“The problem with most physical and chemical pathways for CO2 fixation is that their products are gases and liquids that need to be further liquefied or compressed, and that inevitably leads to additional energy consumption and even more CO2 emissions,” says Haoshen Zhou, senior author of the recently published research. “Instead, we are demonstrating an electrochemical strategy for CO2 fixation that yields solid carbon products, as well as a lithium-CO2 battery that can provide the energy necessary for that process.”

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Carbon dioxideThe global development of industry, technology, and the transportation sector has resulted in massive consumption of fossil fuels. As these fuels are burned, emissions are released—namely carbon dioxide. According to the U.S. Environmental Protection Agency, combustion of petroleum-based products resulted in 6,587 million metric tons of carbon dioxide released into the environment in 2015. But what if we could capture the greenhouse gas and not only convert it, but potentially make a huge profit?

That’s exactly what ECS member Stuart Licht is looking to do.

In a new study, Licht and his team demonstrate using carbon dioxide and solar thermal energy to produce high yields of millimeter-lengths carbon nanotube (CNT) wool at a cost of $660 per ton. According to marketplace values, these CNTs, which have applications ranging from textiles to cement, could then be sold for up to $400,000 per ton.

“We have introduced a new class of materials called ‘Carbon Nanotube Wool,’ which are the first CNTs that can be directly woven into a cloth, as they are of macroscopic length and are cheap to produce,” Licht, a chemistry professor at George Washington University, tells Phys.org. “The sole reactant to produce the CNT wools is the greenhouse gas carbon dioxide.”

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Assuming that the deployment of carbon removal technology will outpace emissions and conquer global climate change is a poor substitute for taking action now, say researchers.

With the current pace of renewable energy deployment and emissions reductions efforts, the world is unlikely to achieve the Paris Climate Agreement’s goal of limiting global warming to 2 degrees Celsius above pre-industrial levels. This trend puts in doubt efforts to keep climate change damages from sea level rise, heat waves, drought, and flooding in check. Removing carbon dioxide from the atmosphere, also known as “negative emissions,” has been thought of as a potential method of fighting climate change.

In their new perspective published in the journal Science, however, researchers from Stanford University explain the risks of assuming carbon removal technologies can be deployed at a massive scale relatively quickly with low costs and limited side effects—with the future of the planet at stake.

“For any temperature limit, we’ve got a finite budget of how much heat-trapping gases we can put into the atmosphere. Relying on big future deployments of carbon removal technologies is like eating lots of dessert today, with great hopes for liposuction tomorrow,” says Chris Field, professor of biology and of earth system science and director of Stanford’s Woods Institute for the Environment.

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Carbon dioxideGlobally, carbon dioxide in the number one contributor to harmful greenhouse gas emissions. These emissions have been linked to the acceleration of climate change, leading to such devastating effects as rising sea levels that displace communities and radical local climates that hurt agriculture.

But what is you could turn that CO2 into baking powder?

That’s what one company in India is setting out to do. A chemical plant in the city of Tuticorin is teaming up with India’s Carbon Clean Solutions to save 60,000 tons of last year’s CO2 emissions.

“I am a businessman. I never thought about saving the planet,” says Ramachadran Gopalan, owner of the plant that is capturing CO2 from coal-powered boilers, to BBC Radio 4. “I needed a reliable stream of CO2, and this was the best way of getting it.”

While Gopalan may not have thought about saving planet, the team at Carbon Clean Solutions has.

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Carbon dioxide emissions account for 80 percent of all greenhouse gases pumped into the environment, totaling in at a staggering 40 tons of CO2 currently emitted from burning fossil fuels. In a response to the high levels of CO2, which have been linked to the accelerating rates in climate change, the U.S. Environmental Protection Agency has called for a 30 percent decrease in emissions of the power sector. Former ECS member Susan Rempe is looking to help the sector achieve that goal through the development of the CO2 Memzyme.

Researchers claim the Memzyme is the only cost-effective way to capture and process CO2. Further, the team states that the Memzyme — which is a membrane with an active layer holding an enzyme — has prefect selectivity.

The development could help capture CO2 from coal-fired power plants and is 10 times thinner than a soap bubble.

When it comes to understanding the factors behind climate change, many scientists point to greenhouse gases – the main contributor being carbon dioxide. From upcycling the greenhouse gas to transforming CO2 into clean burning fuels, electrochemists and solid state scientists are tackling some of the most pressing issues in global warming.

But some researchers are now shifting that spotlight to black carbon (or soot) – the runner-up in factors causing the plant to warm, and one that is often overlooked.

Black carbon is typically created from the running of diesel engines, coal-burning plants, and open biomass incineration. It has been known from its negative impact on health, but it also absorbs light and mixes with water taken from clouds, creating devastating effects.

This from Popular Science:

Eliminating black carbon could stop about 40 percent of global warming. It’s not hard to “scrub” emissions at their source. And because soot only stays in the air for weeks, there would be a near-immediate decrease in the planet’s heating, buying us more time to replace fossil fuels with clean energy. But doing so would trigger a second type of climate change. When black carbon reaches the atmosphere, it’s already mixed with sulfur dioxide and other organic matter. Those particles actually reflect sunlight, causing a “global cooling” effect by preventing that solar radiation from penetrating the lower levels of the atmosphere.

Read the full article.

Researchers are looking to combat this catch 22 by isolating and filtering black carbon.

Reutilizing carbon dioxide to produce clean burning fuels

Carbon dioxide

David Go has always seen himself as something of a black sheep when it comes to his scientific research approach, and his recent work in developing clean alternative fuels from carbon dioxide is no exception.

In 2015, Go and his research team at the University of Notre Dame were awarded a $50,000 grant to purse innovative electrochemical research in green energy technology through the ECS Toyota Young Investigator Fellowship. With a goal of aiding scientists in advancing alternative energies, the fellowship aims to empower young researchers in creating next-generation vehicles capable of utilizing alternative fuels that can lead to climate change action in transportation.

The road less traveled

While advancing research in electric vehicles and fuel cells tend to be the top research areas in sustainable transportation, Go and his team is opting to go down the road less traveled through a new approach to green chemistry: plasma electrochemistry.

(MORE: Read Go’s Meeting Abstract on this topic, entitled “Electrochemical Reduction of CO2(aq) By Solvated Electrons at a Plasma-Liquid Interface.”)

“Our approach to electrochemistry is completely a-typical,” Go, associate professor at the University of Notre Dame, says. “We use a technique called plasma electrochemistry with the aim of processing carbon dioxide – a pollutant – back into more useful products, such as clean-burning fuels.”

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Enzyme-embedded polymer

Lawrence Livermore National Laboratory researcher Sarah Baker measures the amount of methanol produced by the enzyme-embedded polymer.
Image: George Kitrinos/LLNL

A new study has emerged from Lawrence Livermore National Laboratory demonstrating that through the combination of biology and 3-D printing, scientists can turn methane into methanol.

In recent years, methanol has shown a lot of promise as a clean burning fuel. According to the U.S. Environmental Protection Agency, the alcohol’s high-performance and low emission levels could make it an ideal alternative to gasoline for cars.

On the other hand, methane is a potent greenhouse gas that is adding to the acceleration of climate change. While the chemical compound does not stay in the atmosphere as long as carbon dioxide, it is 84 times more potent due to its ability to effectively absorb the sun’s heat and warm the atmosphere. In fact, methane has outpaced carbon dioxide in climate change impact over the least 100 years, with methane’s impact being 25 times greater.

The development from Lawrence Livermore National Laboratory not only provide a clean burning fuel alternative, it effectively helps combat the pressing effects of climate change.

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