A new paper published in the Journal of The Electrochemical Society, “Mixed Conduction Membranes Suppress the Polysulfide Shuttle in Lithium-Sulfur Batteries,” describes a new battery membrane that makes the cycle life of lithium-sulfur batteries comparable to their lithium-ion counterparts.

The research, led by ECS Fellow Sri Narayan, offers a potential solution to one of the biggest barriers facing next generation batteries: how to create a tiny battery that packs a huge punch.

Narayan and Derek Moy, co-author of the paper, believe that lithium-sulfur batteries could be the answer.

The lithium-sulfur battery has been praised for its high energy storage capacity, but hast struggled in competing with the lithium-ion battery when it comes to cycle life. To put it in perspective, a lithium-sulfur battery can be charged between 50 and 100 times; a lithium-ion battery lasts upwards of 1,200 cycles.

To address this issue, the researchers devised the “Mixed Conduction Membrane” (MCM).

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From electric vehicles to grid storage for renewables, batteries are key components in many of tomorrow’s innovations. But current commercialized batteries face problems of price, efficiency, safety, and life-cycle. The television series, NOVA, is exploring many of those issues in the upcoming episode, “Search for the Super Battery.”

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Recent safety concerns with lithium-ion batteries exploding in devices such as the Samsung Galaxy Note 7 phone and hoverboards have many energy researchers looking into this phenomenon for a better understanding of how batteries function when stressed.

A new open access paper published in the Journal of The Electrochemical Society provides some insight into these safety hazards associated with the Li-ion battery by taking a look inside the battery as it is overworked and overcharged.

Overcharging or overheating Li-ion batteries causes the materials inside to breakdown and produce bubbles of oxygen, carbon dioxide, and other gases. As more of these gases are produced, they begin to buildup and cause the battery to swell. That swelling can lead to explosion.

“The battery can either pillow a small amount and keep operating, pillow a lot and cease operation, or keep generating gas and rupture the cell, which can be accompanied by an explosion or fire,” Toby Bond, co-author of the paper, told New Scientist.

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The Samsung Galaxy Note 7 has recently been in the headlines for safety concerns pertaining to its lithium-ion battery. Now, a lawsuit filed in California claims that the issues extend beyond the Note 7, and that many other generations of Samsung smartphones “pose a risk of overheating, fire, and explosion.”

While Samsung claims that the Li-ion safety issues are isolated to only the Note 7, researchers in the field of energy storage are still looking for a way to develop an efficient, non-combustible battery. CBS recently stopped by the University of Maryland to discuss just that with ECS member Erich Wachsman.

Watch the full CBS interview.

In an effort to build safer batteries, Wachsman and his group at the University of Maryland are focusing their research efforts on lithium conducting ceramic discs, which can handle thousands of degrees without any issues.

“Because it’s ceramic, it’s actually not flammable,” says Wachsman, director of the university’s Energy Research Center. “You cannot burn ceramic.”

(MORE: Listen to Wachsman discuss his work in water and sanitation.)

Since the rise of Li-ion battery safety in the news, Wachsman’s research has received more attention from industry. He and his group are currently working on scaling up the technology.

This year marks the 25th anniversary of the commercialization of the lithium-ion battery. To celebrate, we sat down with some of the inventors and pioneers of Li-ion battery technology at the PRiME 2016 meeting.

Speakers John Goodenough (University of Texas at Austin), Stanley Whittingham (Binghamton University), Michael Thackeray (Argonne National Laboratory), Zempachi Ogumi (Kyoto University), and Martin Winter (Univeristy of Muenster) discuss how the Li-ion battery got its start and the impact it has had on society.

Listen to the podcast and download this episode and others for free through the iTunes Store, SoundCloud, or our RSS Feed. You can also find us on Stitcher.

Goodenough was recently named Fellow of ECS at the PRiME 2016 meeting.

John B. Goodenough is recognized internationally as one of the key minds behind the development of the lithium-ion battery; a device that is used to power a huge percentage of today’s electronics and a technology that helped shape the technological frontier.

In a recent interview with the BBC’s Today program’s John Humphrys, the man who helped make the mobile phone possible discusses battery safety in light of exploding Samsung batteries, the Nobel Prize, and his why he doesn’t like cellphones.

“I see the students running around, punching these little tablets, and not talking with one another,” Goodenough says. “I see people going out to dinner and not talking to their partner, rather sitting there talking to someone on their phone, I say, ‘Well, that’s not the way to live.’ Technology is morally neural, it’s what we do with technology that judges us.”

Listen to the full interview here.

Image: NYU’s Jerschow Lab

Researchers from New York University have developed a new technique to give a highly detailed, 3D look inside a lithium-ion battery.

“One particular challenge we wanted to solve was to make the measurements 3D and sufficiently fast, so that they could be done during the battery charging cycle,” explains Alexej Jerschow, co-author of the study that details the development. “This was made possible by using intrinsic amplification processes, which allow one to measure small features within the cell to diagnose common battery failure mechanisms. We believe these methods could become important techniques for the development of better batteries.”

The look that the researchers offer gives new insight to dendrites – the deposits that build up inside a Li-ion battery that can affect performance and safety. To do this, the team used MRI technology to focus the image and took an additional step to improve image quality.

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Image: CC0

Last week, Samsung ordered a global recall of its Galaxy Note 7 phones after investigations into claims of exploding devices revealed faulty lithium-ion batteries. Now, the FAA is strongly urging passengers to forge bringing the device on airliners due to safety risks.

Earlier this year, we spoke to ECS member K.M. Abraham about lithium-ion battery devices and safety concerns associated with them.

“It is safe to say that these well-publicized hazardous events are rooted in the uncontrolled release of the large amount of energy stored in Li-ion batteries as a result of manufacturing defects, inferior active and inactive materials used to build cells and battery packs, substandard manufacturing and quality control practices by a small fraction of cell manufacturers, and user abuses of overcharge and over-discharge, short-circuit, external thermal shocks and violent mechanical impacts,” Abraham said. “Safety hazards of Li-ion batteries occur when the fundamental principle of controlled release of energy on which battery technology is based is compromised by materials and manufacturing defects and operational abuses.”

Read Abraham’s full paper on Li-ion safety and building better batteries.

Image: ANL/Flickr

A new open access paper published in the Journal of The Electrochemical Society entitled, “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment,” finds a new cathode coating for li-ion batteries that could extend the technology’s lifespan.

According to Green Car Congress, the dissolution of transition metals is a major contributor to a li-ion battery’s expedited aging and degradation. However, this new study published in JES by ECS members David Snydacker, Muratahan Aykol, Scott Kirklin, and Christopher Wolverton from Northwestern University makes the case for a new, promising candidate that can act as a stable coating and limit the dissolution of transition metals into the lion electrolyte. That candidate is Li₃PO₄.

This from “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment”:

There are several distinct categories of strategies for limiting TM dissolution from the cathode. Electrolytes can be tailored to reduce reactivity with the cathode. Cathode materials can be doped to control the oxidation states of transition metals. This doping can be applied to the entire cathode particle or just near the surface. Cathode materials can also be covered with surface coatings to limit TM dissolution. Surface coatings can perform a variety of functions for different cathode materials. In this work, we evaluate the ability of coating materials to contain TMs in the cathode and thereby prevent TM dissolution into the electrolyte.

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Image: Mike Mozart/Flickr

Electronic cigarettes have paved a path for smokers to get their nicotine fix in a safer way. However, with recent news reports of the devices exploding into bursts of flames, many consumers now wary of the safety concerns.

E-cigarettes are relatively simple devices. Powered by a battery, an internal heating element vaporizes the liquid solution in the cartridge. But for a New York teen, the process wasn’t as simple as he expected.

Anatomy of an e-cigarette

According to a report by USA Today, the teen pressed the button to activate his e-cigarette and it exploded in his hands like “a bomb went off.”

Investigators expect that the device’s lithium-ion battery malfunctioned. Li-ion batteries, however, are the driving force behind personal electronics, electric vehicles, and even have potential in large-scale grid storage. So why are devices like hoverboards and e-cigarettes experiencing such issues with Li-ion battery safety when so many other applications consider the energy dense, long-life battery a non-safety hazard?

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