Safer, Thinner Lithium Rechargeables

New technology developed by researchers at the University of Michigan has been designed with the intention of preventing fires caused by lithium-ion battery malfunctions.

Researchers are making this possible by creating an advanced barrier between the electrodes in the lithium-ion battery. The barrier is made with nanofibers extracted from Kevlar – the material known for its use in bulletproof vests. The Kevlar nanofibers stifle the growth of metal tendrils that can become unwanted pathways for electrical current.

“Unlike other ultra strong material such as carbon nanotubes, Kevlar is an insulator,” said Nicholas Kotov, the Joseph B. and Florence V. Cejka Professor of Engineering. “This property is perfect for separators that need to prevent shorting between two electrodes.”

Short-circuiting happens in these batteries when holes in the membranes are too big and dendrites poke through to the membrane. They create a path for electrons within the battery, shorting it out.

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Development in Lithium-Ion Batteries

You can thank “dendrites” when your smartphone battery goes from a solid 40 percent charge to completely dead in a matter of 20 minutes. Thankfully, researchers out of Purdue University are researching these dendrites – otherwise known as the slayer of lithium-ion batteries – and developing something that could greatly improve the li-ion.

Dendrites work to destroy lithium-ion batteries by forming an anode electrode and growing until they affect battery performance – potentially resulting in complete battery failure.

The new study out of Purdue University explores this issue with the intention of creating a safer and longer-lasting lithium-ion battery that could be charged within minutes instead of hours.

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Member Spotlight – Stephen Harris

X-ray absorption spectra, interpreted using first-principles electronic structure calculations, provide insight into the solvation of the lithium ion in propylene carbonate.Image: Rich Saykally, Berkeley Labs

X-ray absorption spectra, interpreted using first-principles electronic structure calculations, provide insight into the solvation of the lithium ion in propylene carbonate.
Image: Rich Saykally, Berkeley Labs

The Electrochemical Society’s Stephen Harris, along with a team of researchers from  Berkeley Lab, have found a possible avenue to a better electrolyte for lithium-ion batteries.

Harris – an expert on lithium-ion batteries and chemist at Berkeley Lab’s Materials Science Division – believes that he and his team have unveiled something that could lead to applying lithium-ion batteries to large-scale energy storage.

Researchers around the world know that in order for lithium-ion batteries to store electrical energy for the gird or power electric cars, they must be improved. The team at Berkeley decided to take on this challenge and found surprising results in the first X-ray absorption spectroscopy study of a model lithium electrode, which has provided a better understanding of the liquid electrolyte.

Previous simulations have predicted a tetrahedral solvation structure for the lithium-ion electrolyte, but the new study yields different results.

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Researchers at Nanyang Technological University have developed ultra-fast charging batteries that last 20 years.Credit: Nanyang Technological University

Researchers at Nanyang Technological University have developed ultra-fast charging batteries that last 20 years.
Credit: Nanyang Technological University

If you’re tired of spending more time charging your phone than actually using it, a team of researchers out of Singapore have some good news for you. The group from Nanyang Technological University (NTU) have developed an ultra-fast charging battery – so fast that it can be recharged up to 70 percent in only two minutes.

When comparing this new discovery to the already existing lithium-ion batteries, the new generation has a lifespan of over 20 years – approximately 10 times more than the current lithium-ion battery. Further, each of the existing li-ion’s cycles takes two to four hours to charge, which is significantly more than the new generation’s two minute charge time.

The development will be of particular benefit to the industry of electric vehicles, where people are often put off by the long recharge times and limited battery life. The researchers at NTU believe that drivers of electric vehicles could save tens of thousands on battery replacement costs and will be able to charge their cars in just ten minutes, all in thanks to the new ultra-fast charging battery.

This from NTU:

In the new NTU-developed battery, the traditional graphite used for the anode (negative pole) in lithium-ion batteries is replaced with a new gel material made from titanium dioxide. Titanium dioxide is an abundant, cheap and safe material found in soil. It is commonly used as a food additive or in sunscreen lotions to absorb harmful ultraviolet rays. Naturally found in spherical shape, the NTU team has found a way to transform the titanium dioxide into tiny nanotubes, which is a thousand times thinner than the diameter of a human hair. This speeds up the chemical reactions taking place in the new battery, allowing for super-fast charging.

Read the full article here.

If you’re interested in battery research, take a look at what our Battery Division has to offer.

You can also explore the vast amount of research ECS carries on the technological and scientific breakthroughs in the field of battery by browsing through our digital library or taking a look at this past issue of Interface.

The researchers at Virginia Tech have successfully demonstrated the concept of a sugar biobattery that can completely convert the chemical energy in sugar substrates into electricity. Credit: Virginia Tech University

The researchers at Virginia Tech have successfully demonstrated the concept of a sugar biobattery that can completely convert the chemical energy in sugar substrates into electricity.
Credit: Virginia Tech University

According to new studies, the future of energy storage and conversion may be something that’s sitting in your kitchen cupboard.

A new breakthrough out of Virginia Tech demonstrates that a sugar-powered biobattery has the potential to outperform the current lithium-ion batteries on many fronts.

Not only is the energy density of the sugar-powered battery significantly higher than that of the lithium-ion battery, but the sugar battery is also less costly than the li-ion, refillable, environmentally friendly, and nonflammable.

This from LiveScience:

This nature-inspired biobattery is a type of enzymatic fuel cell (EFC) — an electrobiochemical device that converts chemical energy from fuels such as starch and glycogen into electricity. While EFCs operate under the same general principles as traditional fuel cells, they use enzymes instead of noble-metal catalysts to oxidize their fuel. Enzymes allow for the use of more-complex fuels (such as glucose), and these more-complex fuels are what give EFCs their superior energy density.

Read the full article here.

The scientists hope to increase the power density, extend the lifetime, and reduce the cost of electrode materials in order for this energy-dense sugar biobattery to become the technology of the future.

Find the full findings in this issue of Nature Communications.

Learn more about this topic by reading a recently published open access article via ECS’s Digital Library.

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