The integration of silk into the lithium-ion battery allowed the battery to work for over 10,000 cycles with only a nine percent loss in stability.
Image: ACS Nano

The words “lithium-ion” and “battery” have become almost synonymous recently. While the li-ion battery is used in a multitude of applications, it still does not have a long life without a recharge.

Now, researchers have developed an environmentally friendly way to boost the performance of the li-ion battery by focusing on a material derived from silk.

In the li-ion battery, carbon is the key component for storage. In most situations, graphite takes that role – but it has limited energy capacity. In order to improve the performance of the li-ion battery, researchers looked to replace graphite with a material developed using a sustainable source.

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When it comes to battery research and technology, people are constantly looking toward the lithium-ion battery to see the next big breakthrough. However, researchers at the chemical company BASF are showcasing and older battery type as a strong competitor against the li-ion.

BASF researchers are taking the nickel-metal hydride battery (NiMH) and giving it a boost to lead to cheaper electric cars. The assumption for electric car makers it that improvements in the lithium-ion battery will make cars cheaper and extend their driving range. While that may be true, the NiMH may also be able to do this with a little improvement.

The chemical company has already been able to double the amount of energy these old battery types can store, thus making them comparable to the lithium-ion. Researchers also state that there is still much room for improvement – with the potential to increase energy storage by an additional eight times.

Further, the batteries are set to cost roughly half as much as the cheapest lithium-ion battery.

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The newly developed silicon nanofiber structure allows the battery to be cycled hundreds of times without significant degradation.
Image: Nature Scientific Reports

Electric cars and personal electronics may get the battery boost they need with this new development in lithium-ion batteries.

Researchers from the University of California, Riverside have created silicon nanofibers that are 100 times thinner than human hair, which will provide the potential to boost the amount of energy that can be delivered per unit weight of the batteries.

The research has been detailed in the paper “Towards Scalable Binderless Electrodes: Carbon Coated Silicon Nanofiber Paper via Mg Reduction of Electrospun SiO₂ Nanofibers.”

This from University of California, Riverside:

The nanofibers were produced using a technique known as electrospinning, whereby 20,000 to 40,000 volts are applied between a rotating drum and a nozzle, which emits a solution composed mainly of tetraethyl orthosilicate (TEOS), a chemical compound frequently used in the semiconductor industry. The nanofibers are then exposed to magnesium vapor to produce the sponge-like silicon fiber structure.

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Many of the most influential people of our time are also the most obscure. Take John Goodenough, for example. While he may not be a household name, everyday devices such as laptops and smartphones exist because of his work on lithium-ion batteries.

But even in his 90s, Goodenough isn’t done yet. He’s already invented the lithium-ion’s nervous system, which houses the cobalt-oxide cathode. This is the most important part of every lithium-ion battery, but Goodenough isn’t satisfied with this major scientific feat. Now, he’s looking to go one step further.

This from Quartz:

Today, at 92, Goodenough still goes to his smallish office every day at the University of Texas at Austin. That, he says, is because he’s not finished. Thirty-five years after his blockbuster, the electric car still can’t compete with the internal combustion engine on price. When solar and wind power produce electricity, it must be either used immediately or lost forever—there is no economic stationary battery in which to store the power. Meanwhile, storm clouds are gathering: Oil is again cheap but, like all cyclical commodities, its price will go back up. The climate is warming and becoming generally more turbulent.

Essentially, Goodenough is looking to create a super-battery.

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Voltage profiles of charge-discharge cycles of the Li/Li3PS4/S battery.
Image: Journal of The Electrochemical Society

A team from Japan’s Samsung R&D has worked in collaboration with researchers from the University of Rome to fabricate a novel all solid state Lithium-sulfur battery.

The paper has been recently published in the Journal of The Electrochemical Society. (P.S. It’s Open Access! Read it here.)

The battery’s capacity is around 1,600 mAhg⁻¹, which denotes an initial charge-discharge Coulombic efficiency approaching 99 percent.

Additionally, the battery possesses such beneficial properties as the smooth stripping-deposition of lithium. In contrast to other Li-S cells, the new battery’s activation energy of the charge transfer process is much smaller.

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The development and commercialization of Li-ion batteries in recent decades is without doubt the most important and impressive success of modern electrochemistry.

The Journal of The Electrochemical Society (JES) is publishing focus issues related to IMLB (International Meeting on Lithium Batteries) beginning with the 2014 meeting. Important to note is that this focus issue is completely Open Access, enabling a much broader audience to read these papers than would have access with a subscription-only issue.

Go to the table of contents now!

Twenty-one papers have here been selected for this focus issue. These papers touch upon many important new aspects in the field and illustrate well the wide spectrum of topics that were discussed at the IMLB 2014 meeting.

The most important international conference event in the Li battery community is the biannual International Meeting on Lithium Batteries; a conference series founded by Bruno Scrosati which began 33 years ago. The IMLB meeting can, in fact, be seen as among the most important conferences related to power sources in general.

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Researchers around the world are in a scientific race to develop a near-perfect lithium-ion battery, and a startup from the Massachusetts Institute of Technology (MIT) may have just unlocked the secret.

In 2012, Qichao Hu founded SolidEnergy – a startup that grew out of research and academics from MIT. Qichao started with battery technology that he and ECS member Donald Sadoway developed.

Now, the company is claiming to have built a lithium-ion battery that could change battery technology as we know it.

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You can thank “dendrites” when your smartphone battery goes from a solid 40 percent charge to completely dead in a matter of 20 minutes. Thankfully, researchers out of Purdue University are researching these dendrites – otherwise known as the slayer of lithium-ion batteries – and developing something that could greatly improve the li-ion.

Dendrites work to destroy lithium-ion batteries by forming an anode electrode and growing until they affect battery performance – potentially resulting in complete battery failure.

The new study out of Purdue University explores this issue with the intention of creating a safer and longer-lasting lithium-ion battery that could be charged within minutes instead of hours.

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The aluminum-air battery has the potential to serve as a short-term power source for electric vehicles.
Image: Journal of The Electrochemical Society

A new long-life aluminum-air battery is set to resolve challenges in rechargeable energy storage technology, thanks to ECS member Ryohei Mori.

Mori’s development has yielded a new type of aluminum-air battery, which is rechargeable by refilling with either salt or fresh water.

The research is detailed in an open access article in the Journal of The Electrochemical Society, where Mori explains how he modified the structure of the previous aluminum-air battery to ensure a longer battery life.

Theoretically, metal-air technology can have very high energy densities, which makes it a promising candidate for next-generation batteries that could enable such things as long-range battery-electric vehicles.

However, the long-standing barrier of anode corrosion and byproduct accumulation have halted these batteries from achieving their full potential. Dr. Mori’s recently published paper, “Addition of Ceramic Barriers to Aluminum-Air batteries to Suppress By-product Formation on Electrodes,” details how to combat this issue.

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Scientists out of the University of Waterloo are one step closer to inventing a cheaper, lighter and more powerful rechargeable battery for electric vehicles. At the heart of this discovery lies a breakthrough in lithium-sulfur batteries due to an ultra-thin nanomaterial.

This from the University of Waterloo:

Their discovery of a material that maintains a rechargeable sulfur cathode helps to overcome a primary hurdle to building a lithium-sulfur (Li-S) battery. Such a battery can theoretically power an electric car three times further than current lithium-ion batteries for the same weight – at much lower cost.

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